Electrochemically controlled layer-by-layer deposition of metal-cluster molecular multilayers on gold

被引：97

作者：

Abe, M ^{[1
]}

Michi, T

Sato, A

Kondo, T

Zhou, W

Ye, S

Uosaki, K

Sasaki, Y

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Kita Ku, Sapporo, Hokkaido 0600810, Japan

[2] Hokkaido Univ, Ctr Catalysis Res, Kita Ku, Sapporo, Hokkaido, Japan

[3] Ochanomizu Univ, Dept Chem, Fac Sci, Bunkyo Ku, Tokyo 1128610, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 25期

关键词：

cluster compounds; electron transport; multilayers; nanotechnology; surface chemistry;

D O I：

10.1002/anie.200351334

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Layer-by-layer metal-cluster molecular multilayers are fabricated onto preorganized self-assembled monolayers on Au electrode surfaces. The molecular building block, [Ru3(μ3-O)(μ-CH3COO)6 (bpy)2(CO)] (bpy=4,4′-bipyridine), is applied by displacing the water ligand on the cluster core (see picture), which is precisely controlled through the electrode potential. The series of multilayers transport electrons across the molecularly linked backbone.

引用

页码：2912 / 2915

页数：4

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