A review on thermophysical evaluation of alkali-activated geopolymers

被引:76
作者
Salahuddin, M. B. Mohd [1 ]
Norkhairunnisa, M. [1 ,2 ]
Mustapha, F. [1 ,3 ]
机构
[1] Univ Putra Malaysia, Fac Engn, Dept Aerosp Engn, Upm Serdang 43400, Selangor, Malaysia
[2] Univ Putra Malaysia, Fac Engn, Inst Trop Forestry & Forest Prod INTROP, Upm Serdang 43400, Selangor, Malaysia
[3] Univ Putra Malaysia, Fac Engn, AMRC, Upm Serdang 43400, Selangor, Malaysia
关键词
C. Thermal expansion; Geopolymer; Alumino silicate; Energy; Insulation; OPTIMUM INSULATION-THICKNESS; FLY-ASH; RICE HUSK; THERMAL-PROPERTIES; CONSERVED ENERGY; BUILDING WALLS; METAKAOLIN; EMISSIONS; IMMOBILIZATION; PERFORMANCE;
D O I
10.1016/j.ceramint.2014.11.119
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Recent progress in research on the key thermal expansion properties of amorphous, silica-based, alkali-activated geopolymers and their potential applications are here reviewed and addressed. Besides having great potential as thermal insulators and fire resistant materials since they are not combustible, geopolymers can be applied as interior aircraft components to improve fire resistance, and as coatings for insulator applications and many other potential applications. The raw materials used to make geopolymers are alumino silicates such as fly ash, granulated blast furnace slag, and calcined kaolinite clays. The raw materials can be obtained from biomass waste such as rice husk ash, palm oil ash, and rice husk bark ash. Different raw materials will exhibit different thermal expansion/shrinkage due to their different chemical compositions. In addition, processing of geopolymer material will result in diverse thermal properties due to the different molarity of the alkaline activated solutions used and method of preparation. Interestingly, it was found that the dilatometer curve is influenced by many factors such as aluminosilicate source, silica to alumina ratio, geopolymer mixing ratio, chemical composition and type of geopolymer-such as composite, coating or hybrid. These characteristics are investigated further in this review paper. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:4273 / 4281
页数:9
相关论文
共 78 条
[1]  
Abquez J.M., 2013, EXPERIMENT
[2]   Effect of electricity tariff on the optimum insulation-thickness in building walls as determined by a dynamic heat-transfer model [J].
Al-Sanea, SA ;
Zedan, MF ;
Al-Ajlan, SA .
APPLIED ENERGY, 2005, 82 (04) :313-330
[3]  
Aleman J.V., 2009, APPL CHEM, P1081
[4]  
[Anonymous], 2006, E83113 ASTM ARH NAT
[5]  
[Anonymous], ADV CERAMIC MATRIX C
[6]  
[Anonymous], STAT WORLDS CIT
[7]   Thermal behaviour of geopolymers prepared using class F fly ash and elevated temperature curing [J].
Bakharev, T .
CEMENT AND CONCRETE RESEARCH, 2006, 36 (06) :1134-1147
[8]   Preparation and properties of hydroceramic waste forms made with simulated Hanford low-activity waste [J].
Bao, Y ;
Grutzeck, MW ;
Jantzen, CM .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (12) :3287-3302
[9]   Synthesis and characterisation of materials based on inorganic polymers of alumina and silica: sodium polysialate polymers [J].
Barbosa, VFF ;
MacKenzie, KJD ;
Thaumaturgo, C .
INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2000, 2 (04) :309-317
[10]   Thermal behaviour of inorganic geopolymers and composites derived from sodium polysialate [J].
Barbosa, VFF ;
MacKenzie, KJD .
MATERIALS RESEARCH BULLETIN, 2003, 38 (02) :319-331