What have we learned about topochemical diacetylene polymerizations?

被引:31
作者
Curtis, SM [1 ]
Le, N [1 ]
Nguyen, T [1 ]
Xi, OY [1 ]
Tran, T [1 ]
Fowler, FW [1 ]
Lauher, JW [1 ]
机构
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
关键词
polydiacetylenes; topochemical polymerizations; crystal design; host-guest chemistry; hydrogen bonding;
D O I
10.1080/10610270412331328916
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of five polydiacetylenes have been synthesized via topochemical polymerizations of the corresponding monomers. The requisite structural parameters for the polymerization were achieved by the use of a host-guest co-crystal strategy. The atom trajectories of the polymerization reactions are discussed.
引用
收藏
页码:31 / 36
页数:6
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