Spacer type mediated tunable spin crossover (SCO) characteristics of pyrene decorated 2,6-bis(pyrazol-1-yl)pyridine (bpp) based Fe(II) molecular spintronic modules

被引：13

作者：

Kumar, Kuppusamy Senthil ^{[1
]}

Salitros, Ivan ^{[2
]}

Moreno-Pineda, Eufemio ^{[3
]}

Ruben, Mario ^{[1
,3
]}

机构：

[1] Univ Strasbourg, CNRS, IPCMS, 23 Rue Loess,BP 43, F-67034 Strasbourg 2, France

[2] Slovak Univ Technol Bratislava, Fac Chem & Food Technol, Inst Inorgan Chem Technol & Mat, Bratislava 81237, Slovakia

[3] KIT, Inst Nanotechnol, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany

来源：

DALTON TRANSACTIONS | 2017年 / 46卷 / 30期

关键词：

WIDE THERMAL HYSTERESIS; COORDINATION-COMPOUNDS; IRON(III) COMPLEXES; TRANSITION; ELECTRODES; LIGANDS; DEVICES; STATE; GOLD; LOOP;

D O I：

10.1039/c7dt02219k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A simple "isomer-like" variation of the spacer group in a set of Fe(II) spin crossover (SCO) complexes designed to probe spin state dependence of electrical conductivity in graphene-based molecular spintronic junctions led to the observation of remarkable variations in the thermal-and light-induced magnetic characteristics, paving a simple route for the design of functional SCO complexes with different temperature switching regimes based on a 2,6-bis(pyrazol-1-yl) pyridine ligand skeleton.

引用

收藏

页码：9765 / 9768

页数：4

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