Spacer type mediated tunable spin crossover (SCO) characteristics of pyrene decorated 2,6-bis(pyrazol-1-yl)pyridine (bpp) based Fe(II) molecular spintronic modules

被引：13
作者：
Kumar, Kuppusamy Senthil [1 ]
Salitros, Ivan [2 ]
Moreno-Pineda, Eufemio [3 ]
Ruben, Mario [1 ,3 ]
机构：
[1] Univ Strasbourg, CNRS, IPCMS, 23 Rue Loess,BP 43, F-67034 Strasbourg 2, France
[2] Slovak Univ Technol Bratislava, Fac Chem & Food Technol, Inst Inorgan Chem Technol & Mat, Bratislava 81237, Slovakia
[3] KIT, Inst Nanotechnol, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany
来源：
DALTON TRANSACTIONS | 2017年 / 46卷 / 30期
关键词：
WIDE THERMAL HYSTERESIS; COORDINATION-COMPOUNDS; IRON(III) COMPLEXES; TRANSITION; ELECTRODES; LIGANDS; DEVICES; STATE; GOLD; LOOP;
D O I：
10.1039/c7dt02219k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A simple "isomer-like" variation of the spacer group in a set of Fe(II) spin crossover (SCO) complexes designed to probe spin state dependence of electrical conductivity in graphene-based molecular spintronic junctions led to the observation of remarkable variations in the thermal-and light-induced magnetic characteristics, paving a simple route for the design of functional SCO complexes with different temperature switching regimes based on a 2,6-bis(pyrazol-1-yl) pyridine ligand skeleton.
引用
收藏
页码：9765 / 9768
页数：4
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