Hydrothermally fabricated NdTe hollow shells thermally vaporized on Ni foam for water-splitting in alkaline media

被引:26
作者
Katubi, Khadijah Mohammedsaleh [1 ]
Nisa, Mehar Un [2 ]
Manzoor, Sumaira [2 ]
Ahmad, Zahoor [3 ]
Abid, Abdul Ghafoor [2 ]
Abdullah, Muhammad [4 ]
Al-Buriahi, Mohammed Sultan [5 ]
Ashiq, Muhammad Naeem [1 ]
机构
[1] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Chem, POB 84428, Riyadh 11671, Saudi Arabia
[2] Bahauddin Zakariya Univ, Inst Chem Sci, Multan 60800, Pakistan
[3] Univ Engn & Technol, Dept Chem, Lahore, Pakistan
[4] Govt Coll Univ, Dept Chem, Lahore, Pakistan
[5] Sakarya Univ, Dept Phys, Sakarya, Turkey
来源
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2022年 / 128卷 / 10期
关键词
NdTe; Hollow shell; OER; Alkaline media; OXYGEN REDUCTION REACTION; RECENT PROGRESS; EFFICIENT; ELECTROCATALYSTS; NANOSHEETS; CATALYST; NICO2O4; OER;
D O I
10.1007/s00339-022-05988-x
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electrochemical water-splitting is not sparingly viable due to the slow anodic oxygen evolution reaction (OER). The need to engineer and fabricate electro-catalysts of low over-potential for water oxidation necessitates using readily available technologies and precursors. In the present study, OER electro-catalyst with composition neodymium telluride hollow shells vaporized on Ni Foam (NdTe-HS/NF) is fabricated at a substantially lower energy cost than other abundant metal-containing catalytic structures. The catalytic system functions properly, starting the oxygen evolution process at an over-potential of 301 mV vs. RHE, attaining a current density of 10 mA cm(-2) and a modest Tafel slope of 91 mV dec(-1) is also achieved. This tafel slope value suggests the presence of an electron/proton transfer channel. The catalyst sustains a constant current density over lengthy periods of up to 9 h of water electrolysis testing. Because of an easily accessible production technique, NdTe-HS/NF maintains its integrity, form, and chemical profile even after several hours of nonstop water electrolysis.
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页数:10
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