Study of the spectrum of the Kr-CO weakly bound molecular complex in the millimeter-wavelength range

被引:0
|
作者
Dolgov, A. A. [1 ,2 ]
Panfilov, V. A. [1 ]
Potapov, A. V. [1 ,3 ]
Surin, L. A. [1 ,3 ]
机构
[1] Russian Acad Sci, Inst Spect, Troitsk 142190, Moscow Oblast, Russia
[2] State Univ, Moscow Inst Phys & Technol, Dolgoprudnyi 141700, Moscow Oblast, Russia
[3] Univ Cologne, Inst Phys 1, D-50937 Cologne, Germany
基金
俄罗斯基础研究基金会;
关键词
DER-WAALS COMPLEXES; XE-CO; WAVE SPECTROSCOPY; SPECTROMETER;
D O I
10.1134/S0030400X12050037
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The rotational spectrum of the weakly bound Kr-CO molecular complex formed in a pulsed molecular jet has been measured in the frequency range 112-150 GHz on an intracavity orotron-based spectrometer. The measured b-type transitions include the R branch of the band K = 1-0 with the rotational numbers J from 16 to 25 and the P branch of the band K = 2-1 with the rotational numbers J from 13 to 17. For the K = 1-0 band, we succeeded in recording transitions in complexes that consist of all stable Kr isotopes, i.e., Kr-84-CO, Kr-86-CO, Kr-82-CO, Kr-83-CO, and Kr-80-CO. For the K = 2-1 band, we observed transitions in the two most abundant isotopologues, Kr-84-CO and Kr-86-CO. The obtained data were used to determine the rotational and centrifugal constants of the Kr-CO complex.
引用
收藏
页码:696 / 701
页数:6
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