Synthesis of novel biscrown ethers with rigid cis/trans ethylene bridge

被引：4
作者：
Fan, Jian Quan [1 ]
Jiang, La Sheng [1 ]
Zhang, Min [1 ]
Wei, Na [1 ]
Feng, Ya Hui [1 ]
Han, Shu Juan [1 ]
Wang, Hui [1 ]
机构：
[1] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2008年 / 19卷 / 05期
基金：
中国国家自然科学基金;
关键词：
biscrown ethers; synthesis; characterization; cis/trans configuration;
D O I：
10.1016/j.cclet.2008.03.002
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two novel biscrown ethers with rigid cis/trans ethylene linker were synthesized via Wittig reaction in high yield (about 80%). Their pure cis/trans-isomers were obtained by column chromatography separation. And their structure/configuration was confirmed by H-1 NMR, C-13 NMR, ESI mass spectrum, elemental analysis and UV-vis spectra. (C) 2008 La Sheng Jiang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码：513 / 517
页数：5
相关论文
共 14 条
  • [1] MOLECULAR MECCANO .2. SELF-ASSEMBLY OF [ETA]CATENANES
    AMABILINO, DB
    ASHTON, PR
    BROWN, CL
    CORDOVA, E
    GODINEZ, LA
    GOODNOW, TT
    KAIFER, AE
    NEWTON, SP
    PIETRASZKIEWICZ, M
    PHILP, D
    RAYMO, FM
    REDER, AS
    RUTLAND, MT
    SLAWIN, AMZ
    SPENCER, N
    STODDART, JF
    WILLIAMS, DJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (04) : 1271 - 1293
  • [2] A molecular elevator
    Badjic, JD
    Balzani, V
    Credi, A
    Silvi, S
    Stoddart, JF
    [J]. SCIENCE, 2004, 303 (5665) : 1845 - 1849
  • [3] The bis-barium complex of a butterfly crown ether as a phototunable supramolecular catalyst
    Cacciapaglia, R
    Di Stefano, S
    Mandolini, L
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (08) : 2224 - 2227
  • [4] Highly stable pseudo[2]rotaxanes co-driven by crown ether-ammonium and donor-acceptor interactions
    Feng, DJ
    Li, XQ
    Wang, XZ
    Jiang, XK
    Li, ZT
    [J]. TETRAHEDRON, 2004, 60 (29) : 6137 - 6144
  • [5] Crown ethers: Sensors for ions and molecular scaffolds for materials and biological models
    Gokel, GW
    Leevy, WM
    Weber, ME
    [J]. CHEMICAL REVIEWS, 2004, 104 (05) : 2723 - 2750
  • [6] Syntheses of monofunctional derivatives of m-phenylene-16-crown-5, bis(m-phenylene)-32-crown-10, and m-phenylene-p-phenylene-33-crown-10
    Gibson, HW
    Nagvekar, DS
    Yamaguchi, NI
    Wang, F
    Bryant, WS
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (14) : 4798 - 4803
  • [7] Novel supramolecular charge-transfer systems based on bis(18-crown-6)stilbene and viologen analogues bearing two ammonioalkyl groups
    Gromov, SP
    Vedernikov, AI
    Ushakov, EN
    Lobova, NA
    Botsmanova, AA
    Kuz'mina, LG
    Churakov, AV
    Strelenko, YA
    Alfimov, MV
    Howard, JAK
    Johnels, D
    Edlund, UG
    [J]. NEW JOURNAL OF CHEMISTRY, 2005, 29 (07) : 881 - 894
  • [8] A supramolecular poly[3]pseudorotaxane by self-assembly of a homoditopic cylindrical bis(crown ether) host and a bisparaquat derivative
    Huang, FH
    Gibson, HW
    [J]. CHEMICAL COMMUNICATIONS, 2005, (13) : 1696 - 1698
  • [9] The synthesis of unique structures of tetra-crown ethers through Michael addition
    Huang, ZB
    Kang, TJ
    Chang, SH
    [J]. TETRAHEDRON LETTERS, 2005, 46 (20) : 3461 - 3464
  • [10] Ko SW, 2004, B KOREAN CHEM SOC, V25, P957
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