Effect of coal properties on HCN and NH3 release during coal pyrolysis

被引：3

作者：

Chang, LP ^{[1
]}

Feng, ZH ^{[1
]}

Xie, KC ^{[1
]}

机构：

[1] Taiyuan Univ Technol, Key Lab Coal Sci & Technol, Minist Educ & Shanxi Prov, Taiyuan 030024, Shanxi, Peoples R China

来源：

ENERGY SOURCES | 2005年 / 27卷 / 15期

基金：

中国国家自然科学基金;

关键词：

coal; properties; pyrolysis; NOx precursors; HCN; NH3;

D O I：

10.1080/009083190913953

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The formation of HCN and NH3 from fuel nitrogen during pyrolysis was studied in a prefilled reactor system with slow (temperature-programmed) heating and in a drop-in reactor system with a rapid heating rate. The experimental results indicate that the formation of HCN and NH3 is obviously affected by coal properties. The effects of these coal properties vary with the heating fashion. Coal rank, characteristic of char residue, surface characteristics, and composition of the coal are important factors influencing the formation of HCN and NH3 during pyrolysis.

引用

页码：1399 / 1407

页数：9

共 11 条

[1] IMPORTANCE OF SOLID-FUEL PROPERTIES TO NITROGEN-OXIDE FORMATION THROUGH HCN AND NH3 IN SMALL-PARTICLE COMBUSTION
AHO, MJ
HAMALAINEN, JP
TUMMAVUORI, JL
[J]. COMBUSTION AND FLAME, 1993, 95 (1-2) : 22 - 30
[2] Effect of operating parameters on HCN and NH3 release from Australian and Chinese coals during temperature-programmed pyrolysis
Chang, LP
Feng, ZH
Xie, KC
[J]. ENERGY SOURCES, 2003, 25 (07): : 703 - 712
[3] Conversion of fuel nitrogen through HCN and NH3 to nitrogen oxides at elevated pressure
Hamalainen, JP
Aho, MJ
[J]. FUEL, 1996, 75 (12) : 1377 - 1386
[4] RELATION BETWEEN FUNCTIONAL FORMS OF COAL NITROGEN AND FORMATION OF NO(X) PRECURSORS DURING RAPID PYROLYSIS
KAMBARA, S
TAKARADA, T
YAMAMOTO, Y
KATO, K
[J]. ENERGY & FUELS, 1993, 7 (06) : 1013 - 1020
[5] NITROGEN EVOLUTION FROM COAL, PEAT AND WOOD DURING GASIFICATION - LITERATURE-REVIEW
LEPPALAHTI, J
KOLJONEN, T
[J]. FUEL PROCESSING TECHNOLOGY, 1995, 43 (01) : 1 - 45
[6] Formation of NOx and SOx precursors during the pyrolysis of coal and biomass.: Part III.: Further discussion on the formation of HCN and NH3 during pyrolysis
Li, CZ
Tan, LL
[J]. FUEL, 2000, 79 (15) : 1899 - 1906
[7] Formation of NOx and SOx precursors during the pyrolysis of coal and biomass.: Part I.: Effects of reactor configuration on the determined yields of HCN and NH3 during pyrolysis
Tan, LL
Li, CZ
[J]. FUEL, 2000, 79 (15) : 1883 - 1889
[8] Formation of NOx and SOx precursors during the pyrolysis of coal and biomass.: Part II.: Effects of experimental conditions on the yields of NOx and SOx precursors from the pyrolysis of a Victorian brown coal
Tan, LL
Li, CZ
[J]. FUEL, 2000, 79 (15) : 1891 - 1897
[9] Key factors for formation of N-2 from low-rank coals during fixed fed pyrolysis: Pyrolysis conditions and inherent minerals
Wu, ZH
Ohtsuka, Y
[J]. ENERGY & FUELS, 1997, 11 (04) : 902 - 908
[10] Formation of NOx and SOx precursors during the pyrolysis of coal and biomass.: Part IV.: Pyrolysis of a set of Australian and Chinese coals
Xie, ZL
Feng, J
Zhao, W
Xie, KC
Pratt, KC
Li, CZ
[J]. FUEL, 2001, 80 (15) : 2131 - 2138

← 1 2 →