Probing Intermolecular Interactions in Binary Liquid Mixtures Using Femtosecond Laser-Induced Self-Defocusing

被引：5
|
作者：
Maurya, Sandeep Kumar [1 ]
Das, Dhiman [1 ]
Goswami, Debabrata [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Kanpur, Uttar Pradesh, India
来源：
APPLIED SPECTROSCOPY | 2016年 / 70卷 / 10期
关键词：
High repetition femtosecond pulses; nonlinear optics; thermal lens; spectroscopy; binary liquids; THERMAL-LENS SPECTROSCOPY; OVERTONE ABSORPTION; HIGH-SENSITIVITY; SINGLE-BEAM; Z-SCAN; WATER; EFFUSIVITY; VOLUMES; SAMPLES;
D O I：
10.1177/0003702816643547
中图分类号：
TH7 [仪器、仪表];
学科分类号：
0804 ; 080401 ; 081102 ;
摘要：
Photothermal behavior of binary liquid mixtures has been studied using a high repetition rate (HRR) Z-scan technique with femtosecond laser pulses. Changes in the peak-valley difference in transmittance (Delta TP-V) for closed aperture Z-scan experiments are indicative of thermal effects induced by HRR femtosecond laser pulses. We show such indicative results can have a far-reaching impact on molecular properties and intermolecular interactions in binary liquid mixtures. Spectroscopic parameters derived from this experimental technique show that the combined effect of physical and molecular properties of the constituent binary liquids can be related to the components of the binary liquid.
引用
收藏
页码：1655 / 1661
页数：7
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