Engineering high refractive index sensitivity through the internal and external composition of bimetallic nanocrystals

被引：12

作者：

Smith, Alison F. ^{[1
,2
]}

Harvey, Samantha M. ^{[1
]}

Skrabalak, Sara E. ^{[1
]}

Weiner, Rebecca G. ^{[1
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[2] NAVSEA Crane, Crane, IN 47522 USA

来源：

NANOSCALE | 2016年 / 8卷 / 38期

基金：

美国国家科学基金会;

关键词：

SURFACE-PLASMON RESONANCE; CHEMICAL-STABILITY; OPTICAL-CONSTANTS; CO-REDUCTION; NANOSTRUCTURES; NANOPARTICLES; SHAPE; SIZE; GOLD; AG;

D O I：

10.1039/c6nr04085c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High refractive index sensitivity (RIS) of branched Au-Pd nanocrystals (NCs) is engineered through lowering the dielectric dispersion at the NC resonant wavelength with internal or external atomic % Pd. To our knowledge, these NCs display the highest ensemble RIS measurement for colloids with LSPR maximum band positions <= 900 nm, and these results are corroborated with FDTD computations.

引用

页码：16841 / 16845

页数：5

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