An improved method for the preparation of tetra-coordinate platinum(II) chloro-complexes containing bidentate or terdentate ligands starting from cis/trans-[PtCl2(SMe2)2]

被引：6

作者：

Annibale, G ^{[1
]}

Bortoluzzi, M ^{[1
]}

Marangoni, G ^{[1
]}

Pitteri, B ^{[1
]}

机构：

[1] Univ Ca Foscari Venice, Dipartimento Chim, I-31023 Venice, Italy

来源：

TRANSITION METAL CHEMISTRY | 2005年 / 30卷 / 06期

关键词：

D O I：

10.1007/s11243-005-6275-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An improved method for the preparation of differently charged chelate Pt(II)chloro-complexes is reported. All the complexes have been obtained rapidly and in high yield, by simply reacting equimolar amounts of cis/trans-dichlorobis(dimethylsulphide)platinum(II) with the chelate ligand in an appropriate solvent (CH2Cl2, MeOH or H2O). The ligands chosen were: 1,2-bis(diphenylphosphino)ethane (P-P), pyridine-2-carboxylate (N-O-), 2-[(methylthio)methyl]pyridine (N-S), 1,10-phenanthroline (N-N), bis(2-pyridylmethyl)sulphide (N-S-N), di-(2-picolyl)amine (N-N-N), pyridine-2,6-dicarboxylate (O-N-O2-) and 2,6-bis(methylthiomethyl)pyridine (S-N-S).

引用

页码：748 / 750

页数：3

共 16 条

[1]

ANNIBALE G, 1985, GAZZ CHIM ITAL, V115, P279

[2]

Annibale G, 2004, INORG SYN, V34, P76

[3] THE REACTIONS BETWEEN TETRACHLOROPLATINATE(II) ANION AND BIDENTATE SULPHUR-NITROGEN CHELATING-AGENTS - A DIRECT ROUTE FOR THE SYNTHESIS OF THE NEUTRAL DICHLORO SPECIES [J].

BALDO, A ;

CHESSA, G ;

MARANGONI, G ;

PITTERI, B .

POLYHEDRON, 1985, 4 (08) :1429-1431

[4] CHEMISTRY OF PYRIDINE .2. REACTION OF 1-ALKOXYPICOLINIUM SALTS WITH MERCAPTIDE AND THIOPHENOXIDE IONS [J].

BAUER, L ;

GARDELLA, LA .

JOURNAL OF ORGANIC CHEMISTRY, 1963, 28 (05) :1323-&

[5] BIS-MU-[BIS(DIPHENYLPHOSPHINO)METHANE]-BIS(HALOGENOPLATINUM)(PT-PT) - DIMERIC COMPLEXES OF PLATINUM(I) CONTAINING A PLATINUM-PLATINUM BOND [J].

BROWN, MP ;

PUDDEPHATT, RJ ;

RASHIDI, M ;

SEDDON, KR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (09) :951-955

[6] BINDING ABILITY OF 2,6-BIS(METHYLTHIOMETHYL)PYRIDINE WITH PROTON, PALLADIUM(II) AND COPPER(II) IN AQUEOUS-SOLUTIONS [J].

CANOVESE, L ;

CHESSA, G ;

MARANGONI, G ;

PITTERI, B ;

UGUAGLIATI, P ;

VISENTIN, F .

INORGANICA CHIMICA ACTA, 1991, 186 (01) :79-86

[7] SYNTHESIS AND CHARACTERIZATION OF ANIONIC PLATINUM(II) COMPLEXES CONTAINING THE TRIDENTATE LIGAND PYRIDINE-2,6-DICARBOXYLATO (O-N-O) AND THE KINETICS OF CHLORIDE DISPLACEMENT FROM [PT(O-N-O)CL]- [J].

CATTALINI, L ;

CHESSA, G ;

MARANGONI, G ;

PITTERI, B ;

CELON, E .

INORGANIC CHEMISTRY, 1989, 28 (10) :1944-1947

[8] SYNTHESIS AND CHARACTERIZATION OF SQUARE-PLANAR PLATINUM(II) AND PALLADIUM(II) COMPLEXES WITH PYRIDINE-2,6-DICARBOXYLIC ACID (H2DIPIC) - X-RAY CRYSTAL-STRUCTURE OF TRANS-NA2[PT(DIPIC)2]-6H2O AND K[PT(DIPIC)I]-1/2H2O [J].

CHESSA, G ;

MARANGONI, G ;

PITTERI, B ;

BERTOLASI, V ;

GILLI, G ;

FERRETTI, V .

INORGANICA CHIMICA ACTA, 1991, 185 (02) :201-210

[9] SULPHUR-NITROGEN CHELATING AGENTS .2. METAL COMPLEXES OF 2-(2-METHYLTHIOETHYL)PYRIDINE [J].

CHIA, PSK ;

LIVINGST.SE ;

LOCKYER, TN .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1966, 19 (10) :1835-&

[10] FACILE SYNTHESIS OF ISOMERICALLY PURE cis-DICHLORODIAMMINEPLATINUM(II)CISPLATIN [J].

Kukushkin, VY ;

Oskarsson, A ;

Elding, LI ;

Farrell, N ;

Dunham, S ;

Lippard, SJ .

INORGANIC SYNTHESES, VOL 32, 1998, 32 :141-144

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