Ruthenium complexes with a pyrazole-phosphine ligand

被引：8

作者：

Alshakova, Iryna D. ^{[1
]}

Korobkov, Ilya ^{[2
]}

Kuzmina, Lyudmila G. ^{[3
]}

Nikonov, Georgii I. ^{[1
]}

机构：

[1] Brock Univ, Chem Dept, 1812 Sir Isaac Brock Way, Niagara Region, ON L2S 3A1, Canada

[2] Univ Ottawa, Fac Sci, Xray Core Facil, 150 Louis Pasteur, Ottawa, ON K1N 6N5, Canada

[3] RAS, Inst Gen & Inorgan Chem, Leninskii Prosp 31, Moscow 119991, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 853卷

基金：

加拿大自然科学与工程研究理事会;

关键词：

Phosphine; Pyrazole; Ruthenium; Transfer hydrogenation; Bifunctional catalysis; ASYMMETRIC TRANSFER HYDROGENATION; HALF-SANDWICH COMPLEX; CATALYSTS; KETONES; NITRILES;

D O I：

10.1016/j.jorganchem.2017.10.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A bifunctional pyrazole-based phosphine ligand was synthesized and applied to preparation of a series of ruthenium complexes. Application of the latter to transfer hydrogenation of acetophenone showed moderate activity. X-ray studies of two ruthenium complexes were carried out. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：68 / 73

页数：6

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