Infrared spectrum and structure of the gold dihydroxide molecule

被引：11

作者：

Wang, XF ^{[1
]}

Andrews, L ^{[1
]}

机构：

[1] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 31期

关键词：

D O I：

10.1039/b506970j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of laser-ablated gold atoms with H2O2 and H-2 + O-2 mixtures give four new infrared absorptions, which match the four most intense vibrational frequencies calculated for Au(OH)(2) using density functional theory; the calculations find a C-2h structure and substantial covalent bonding character for the Au(OH)(2) molecule, which is probably due to the high electron affinity of gold.

引用

页码：4001 / 4003

页数：3

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