Microstructure and mechanical properties of boron carbide/graphene nanoplatelets composites fabricated by hot pressing

被引:17
作者
Wang, Aiyang [1 ]
He, Qianglong [1 ]
Liu, Chun [1 ]
Hu, Lanxin [1 ]
Tian, Tian [1 ]
Zhang, Zhixiao [2 ]
Xiong, Yan [3 ]
Wang, Weimin [1 ]
Wang, Hao [1 ]
Fu, Zhengyi [1 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
[2] Hebei Univ Engn, Coll Mat Sci & Engn, Handan 056038, Peoples R China
[3] Hubei Univ Technol, Sch Mat Sci & Engn, Hubei Prov Key Lab Green Mat Light Ind, Wuhan 430023, Peoples R China
基金
中国国家自然科学基金;
关键词
B4C-GNPs; Hot pressing; Mechanical properties; Toughening mechanisms; FRACTURE-TOUGHNESS; CARBIDE COMPOSITES; GRAPHENE SHEETS; CERAMICS; GRAPHITE; CONDUCTIVITY; STRENGTH; OXIDE;
D O I
10.1016/j.ceramint.2019.12.007
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this study, boron carbide (B4C)-graphene nanoplatelets (GNPs) composites, with enhanced strength and toughness, were fabricated by hot pressing at 1950 degrees C under a pressure of 30 MPa for 1 h. Microstructure analysis revealed that the GNPs are homogenously dispersed within the B4C matrix. Raman spectroscopy and electron microscopy showed the orientation of the GNPs in the composites. The effects of the amount of GNPs on the microstructure and mechanical properties of the composites were also investigated. The optimal mechanical properties were achieved using 1 wt% GNPs. The relative density, Vickers hardness, flexure strength, and fracture toughness of the B4C-GNPs composite ceramic were found to be 99.12%, 32.8 GPa, 508 MPa, and 4.66 MPa m(1/2) , respectively. The main toughening mechanisms included crack deflection in three dimensions, GNPs pull-out, and crack bridging. The curled and semi-wrapped GNPs encapsulated individual B4C grains to resist GNPs pull-out and to deflect propagating cracks.
引用
收藏
页码:7879 / 7887
页数:9
相关论文
共 42 条
[1]   Exfoliation of graphene sheets via high energy wet milling of graphite in 2-ethylhexanol and kerosene [J].
Al-Sherbini, Al-Sayed ;
Bakr, Mona ;
Ghoneim, Iman ;
Saad, Mohamed .
JOURNAL OF ADVANCED RESEARCH, 2017, 8 (03) :209-215
[2]   Effect of graphene nano-platelet reinforcement on the mechanical properties of hot pressed boron carbide based composite [J].
Alexander, Rajath ;
Murthy, T. S. R. Ch. ;
Ravikanth, K. V. ;
Prakash, Jyoti ;
Mahata, Tarasankar ;
Bakshi, Srinivasa Rao ;
Krishnan, Madangopal ;
Dasgupta, Kinshuk .
CERAMICS INTERNATIONAL, 2018, 44 (08) :9830-9838
[3]   Low energy pure shear milling: A method for the preparation of graphite nano-sheets [J].
Antisari, M. Vittori ;
Montone, A. ;
Jovic, N. ;
Piscopiello, E. ;
Alvani, C. ;
Pilloni, L. .
SCRIPTA MATERIALIA, 2006, 55 (11) :1047-1050
[4]   Superior thermal conductivity of single-layer graphene [J].
Balandin, Alexander A. ;
Ghosh, Suchismita ;
Bao, Wenzhong ;
Calizo, Irene ;
Teweldebrhan, Desalegne ;
Miao, Feng ;
Lau, Chun Ning .
NANO LETTERS, 2008, 8 (03) :902-907
[5]   Toughened and strengthened silicon carbide ceramics by adding graphene-based fillers [J].
Belmonte, Manuel ;
Nistal, Andres ;
Boutbien, Pierre ;
Roman-Manso, Benito ;
Osendi, Maria I. ;
Miranzo, Pilar .
SCRIPTA MATERIALIA, 2016, 113 :127-130
[6]   Reinforcing mechanism of graphene at atomic level: Friction, crack surface adhesion and 2D geometry [J].
Chen, Shu Jian ;
Li, Chen Yang ;
Wang, Quan ;
Duan, Wen Hui .
CARBON, 2017, 114 :557-565
[7]   Microstructure and fracture toughness of Si3N4 + graphene platelet composites [J].
Dusza, Jan ;
Morgiel, Jerzy ;
Duszova, Annamaria ;
Kvetkova, Lenka ;
Nosko, Martin ;
Kun, Peter ;
Balazsi, Csaba .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2012, 32 (12) :3389-3397
[8]   Graphene Based Oxide Ceramic Composites with High Mechanical and Functional Performance: from Preparation to Property [J].
Fan Yu-Chi ;
Wang Lian-Jun ;
Jiang Wan .
JOURNAL OF INORGANIC MATERIALS, 2018, 33 (02) :138-146
[9]   The effect of homogeneously dispersed few-layer graphene on microstructure and mechanical properties of Al2O3 nanocomposites [J].
Fan, Yuchi ;
Estili, Mehdi ;
Igarashi, Ginga ;
Jiang, Wan ;
Kawasaki, Akira .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2014, 34 (02) :443-451
[10]   Highly Conductive Few-Layer Graphene/Al2O3 Nanocomposites with Tunable Charge Carrier Type [J].
Fan, Yuchi ;
Jiang, Wan ;
Kawasaki, Akira .
ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (18) :3882-3889