Synthesis, characterization, elastic, and electro-magnetic properties of MFe2O4 ferrites (M =Co2+, Ni2+, Cu2+, Mg2+ and Zn2+) via sucrose auto-combustion

被引：12
|
作者：
Gabal, M. A. [1 ,2 ]
Al-Mutairi, Ebtesam [1 ]
Al Angari, Y. M. [1 ]
Awad, A. [2 ]
Al-Juaid, A. A. [3 ]
Saeed, Abdu [4 ]
机构：
[1] King Abdulaziz Univ, Fac Sci, Chem Dept, Jeddah, Saudi Arabia
[2] Benha Univ, Fac Sci, Chem Dept, Banha, Egypt
[3] Univ Jeddah, Fac Sci, Chem Dept, Jeddah, Saudi Arabia
[4] King Abdulaziz Univ, Fac Sci, Phys Dept, Jeddah, Saudi Arabia
来源：
JOURNAL OF MATERIALS RESEARCH | 2022年 / 37卷 / 14期
关键词：
LOW-TEMPERATURE SYNTHESIS; MAGNETIC-PROPERTIES; DIELECTRIC-PROPERTIES; ELECTRICAL-PROPERTIES; COBALT SUBSTITUTION; CO; NANOPARTICLES; SPECTROSCOPY; COFE2O4; CR3+;
D O I：
10.1557/s43578-022-00624-z
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Ferrites; MFe2O4 (M= Co, Ni, Cu, Mg ,and Zn) nanocrystals were prepared using sucrose auto-combustion. X-ray diffraction showed complete formation of ferrites with tetragonal structure for CuFe2O4 and cubic for all others. Fourier transform-infrared confirmed ferrites'formation, and the obtained data were used to estimate the different elastic properties. Transmission electron microscopy exhibited agglomerated spherically shaped clusters for CoFe2O4, MgFe2O4, and ZnFe2O4 while NiFe2O4 and CuFe2O4 showed cubic morphology. Magnetic measurements via vibrating sample magnetometer revealed ferromagnetic properties of all ferrites except for ZnFe2O4 indicating paramagnetic one. The coercivity measurements indicated magnetically hard ferrites for CoFe2O4 and CuFe2O4, while others showed soft magnetic. ac-conductivity indicated semiconducting properties with a magnetic phase transition from ferro- to paramagnetic for all ferrites except for CoFe2O4. The deviation from Arrhenius plots at > 500 K revealed the conduction mechanism change from electron hopping to polaron conduction. This change was also proved via conductivity vs. frequency and through dielectric relaxation.
引用
收藏
页码：2257 / 2270
页数：14
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