Compromising Science by Ignorant Instrument Calibration-Need to Revisit Half a Century of Published XPS Data

被引：744

作者：

Greczynski, Grzegorz ^{[1
]}

Hultman, Lars ^{[1
]}

机构：

[1] Linkoping Univ, Thin Film Phys Div, Dept Phys Chem & Biol IFM, S-58183 Linkoping, Sweden

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 13期

基金：

瑞典研究理事会;

关键词：

binding energy; C 1s peak; chemical state; referencing; XPS; RAY PHOTOELECTRON-SPECTROSCOPY; ADVENTITIOUS CARBON; BINDING-ENERGY; STATE; CU;

D O I：

10.1002/anie.201916000

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

X-ray photoelectron spectroscopy (XPS) is an indispensable technique in modern materials science for the determination of chemical bonding as evidenced by more than 10 000 XPS papers published annually. A literature survey reveals that in the vast majority of cases an incorrect referencing of the binding energy scale is used, neglecting warnings that have been formulated from the early days of the technique. Consequences for the data reliability are disastrous and decades of XPS work require revisiting. The purpose of this Viewpoint is to highlight the existing problems, review the criticism and suggest ways forward.

引用

页码：5002 / 5006

页数：5

共 27 条

[1]

[Anonymous], 1887, Ann. Phys, DOI DOI 10.1002/ANDP.18872670707

[2]

[Anonymous], 2015, Standard Guide to Charge Control and Charge Referencing Techniques in X-Ray Photoelectron Spectroscopy

[3] Practical guides for x-ray photoelectron spectroscopy: First steps in planning, conducting, and reporting XPS measurements [J].

Baer, Donald R. ;

Artyushkova, Kateryna ;

Brundle, Christopher Richard ;

Castle, James E. ;

Engelhard, Mark H. ;

Gaskell, Karen J. ;

Grant, John T. ;

Haasch, Richard T. ;

Linford, Matthew R. ;

Powell, Cedric J. ;

Shard, Alexander G. ;

Sherwood, Peter M. A. ;

Smentkowski, Vincent S. .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2019, 37 (03)

[4]

Cedric J. P., 2012, NIST Data Resources for X-Ray Photoelectron Spectroscopy

[5] MEASUREMENT AND CALCULATION OF POLARIZATION AND POTENTIAL-ENERGY EFFECTS ON CORE-ELECTRON BINDING-ENERGIES IN SOLIDS - X-RAY PHOTOEMISSION OF RARE-GASES IMPLANTED IN NOBLE-METALS [J].

CITRIN, PH ;

HAMANN, DR .

PHYSICAL REVIEW B, 1974, 10 (12) :4948-4963

[6] XPS in industry-Problems with binding energies in journals and binding energy databases [J].

Crist, B. Vincent .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2019, 231 :75-87

[7] EXTERNAL STANDARDS IN X-RAY PHOTOELECTRON SPECTROSCOPY - COMPARISON OF GOLD, CARBON, AND MOLYBDENUM TRIOXIDE [J].

DIANIS, WP ;

LESTER, JE .

ANALYTICAL CHEMISTRY, 1973, 45 (08) :1416-1420

[8]

Einstein A, 1905, ANN PHYS-BERLIN, V17, P132

[9] ELECTRON SPECTROSCOPY AND CHEMICAL BINDING [J].

FAHLMAN, A ;

HAMRIN, K ;

HEDMAN, J ;

NORDBERG, R ;

NORDLING, C ;

SIEGBAHN, K .

NATURE, 1966, 210 (5031) :4-&

[10] X-ray photoelectron spectroscopy: Towards reliable binding energy referencing [J].

Greczynski, G. ;

Hultman, L. .

PROGRESS IN MATERIALS SCIENCE, 2020, 107

← 1 2 3 →