2-Azabicyclo[2.2.1]hept-5-enes from 7-azabicyclo[2.2.1]heptadienes by tandem intermolecular radical addition-homoallylic radical rearrangement

被引：12
|
作者：
Hodgson, DM
Bebbington, MWP
Willis, P
机构：
[1] Univ Oxford, Dyson Perrins Lab, Dept Chem, Oxford OX1 3QY, England
[2] AstraZeneca, R&D Charnwood, Loughborough, Leics, England
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 10期
关键词：
D O I：
10.1039/b101984h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Addition of thiols to 7-azabicyclo[2.2.1]heptadienes such as 16 leads exclusively to 7-thio-substituted 2-azabicyclo[2.2.1]-hept-5-enes 17 in good yields via tandem intermolecular radical addition-homoallylic radical rearrangement.
引用
收藏
页码：889 / 890
页数：2
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