Oxidation of 5-hydroxymethylfurfural over supported Pt, Pd and Au catalysts

被引：349
|
作者：
Davis, Sara E. [1 ]
Houk, Levi R. [2 ,3 ]
Tamargo, Erin C. [1 ]
Datye, Abhaya K. [2 ,3 ]
Davis, Robert J. [1 ]
机构：
[1] Univ Virginia, Dept Chem Engn, Charlottesville, VA 22904 USA
[2] Univ New Mexico, Ctr Microengineered Mat, Albuquerque, NM 87131 USA
[3] Univ New Mexico, Dept Chem & Nucl Engn, Albuquerque, NM 87131 USA
来源：
CATALYSIS TODAY | 2011年 / 160卷 / 01期
基金：
美国国家科学基金会;
关键词：
5-Hydroxymethylfurfural; Oxidation; Gold catalysis; Heterogeneous catalysis; Biomass; AEROBIC OXIDATION; 2,5-FURANDICARBOXYLIC ACID; SELECTIVE OXIDATION; BIOMASS; CHEMICALS; 5-HYDROXYMETHYL-2-FURALDEHYDE; DEHYDRATION; GLYCEROL; FRUCTOSE;
D O I：
10.1016/j.cattod.2010.06.004
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Supported Pt, Pd, and Au catalysts were evaluated in the aqueous-phase oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) at 295K and high pH in a semibatch reactor. The intermediate reaction product 5-hydroxymethyl-2-furancarboxylic acid (HFCA) was formed in high yield over Au/C and Au/TiO2 at 690 kPa O-2, 0.15M HMF and 0.3M NaOH, but did not continue to react substantially to FDCA at the specified O-2 pressure and base concentration. In contrast, the final reaction product FDCA was formed over Pt/C and Pd/C under identical conditions. The initial turnover frequency of HMF conversion was an order of magnitude greater on Au catalysts compared to either Pt or Pd. Increasing the O-2 pressure and NaOH concentration facilitated the conversion of HFCA to FDCA over the supported Au. The significant influence of base concentration on the product distribution indicates an important role of OH-in the activation, oxidation and degradation of HMF. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：55 / 60
页数：6
相关论文
共 50 条
  • [1] Au and Pt nanoparticles supported on functionalized carbon nanofibers as catalysts for the oxidation of 5-hydroxymethylfurfural
    Davis, Sara E.
    Sanchez, Angelica
    Gosselink, Rob W.
    Bitter, Johannes H.
    de Jong, Krijn P.
    Datye, Abhaya K.
    Davis, Robert J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [2] Oxidation of 5-Hydroxymethylfurfural on Supported Ag, Au, Pd and Bimetallic Pd-Au Catalysts: Effect of the Support
    German, Dmitrii
    Pakrieva, Ekaterina
    Kolobova, Ekaterina
    Carabineiro, Sonia A. C.
    Stucchi, Marta
    Villa, Alberto
    Prati, Laura
    Bogdanchikova, Nina
    Cortes Corberan, Vicente
    Pestryakov, Alexey
    CATALYSTS, 2021, 11 (01) : 1 - 20
  • [3] On the mechanism of selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over supported Pt and Au catalysts
    Davis, Sara E.
    Zope, Bhushan N.
    Davis, Robert J.
    GREEN CHEMISTRY, 2012, 14 (01) : 143 - 147
  • [4] Oxidation of 5-Hydroxymethylfurfural over Supported Palladium-Containing Catalysts
    K. L. Timofeev
    D. P. Morilov
    T. S. Kharlamova
    Kinetics and Catalysis, 2023, 64 : 439 - 448
  • [5] Oxidation of 5-Hydroxymethylfurfural over Supported Palladium-Containing Catalysts
    Timofeev, K. L.
    Morilov, D. P.
    Kharlamova, T. S.
    KINETICS AND CATALYSIS, 2023, 64 (04) : 439 - 448
  • [6] Design strategy for effective supported Au-Pd catalysts for selective oxidation of 5-hydroxymethylfurfural under mild conditions
    Kharlamova, Tamara S.
    Timofeev, Konstantin L.
    Morilov, Denis P.
    Salaev, Mikhail A.
    Stadnichenko, Andrey I.
    Stonkus, Olga A.
    Vodyankina, Olga V.
    REACTION CHEMISTRY & ENGINEERING, 2024, 9 (10): : 2691 - 2709
  • [7] Hydrogenolysis of 5-hydroxymethylfurfural over alumina-supported catalysts
    Duarte, Diana P.
    Martinez, Ramiro
    Hoyos, Luis J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [8] Efficient Aerobic Oxidation of 5-Hydroxymethylfurfural in Aqueous Media with Au-Pd Supported on Zinc Hydroxycarbonate
    Gui, Zhenyou
    Cao, Wenrong
    Saravanamurugan, Shunmugavel
    Riisager, Anders
    Chen, Lifang
    Qi, Zhiwen
    CHEMCATCHEM, 2016, 8 (23) : 3636 - 3643
  • [9] Oxidation of glycerol using supported Pt, Pd and Au catalysts
    Carrettin, S
    McMorn, P
    Johnston, P
    Griffin, K
    Kiely, CJ
    Hutchings, GJ
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (06) : 1329 - 1336
  • [10] Electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid on supported Au and Pd bimetallic nanoparticles
    Chadderdon, David J.
    Xin, Le
    Qi, Ji
    Qiu, Yang
    Krishna, Phani
    More, Karren L.
    Li, Wenzhen
    GREEN CHEMISTRY, 2014, 16 (08) : 3778 - 3786
12345