Possible deviations from the O(4) limit of the vibron model in diatomic molecules

被引:6
作者
Pan, F [1 ]
Zhang, X
Draayer, JP
机构
[1] Liaoning Normal Univ, Dept Phys, Dalian 116029, Peoples R China
[2] Louisiana State Univ, Dept Phys & Astron, Baton Rouge, LA 70803 USA
基金
中国国家自然科学基金; 美国国家科学基金会;
关键词
U (4) vibron model; U (3) <-> O (4) transitional theory; O (4) limit; vibrational spectra of diatomic molecules;
D O I
10.1016/S0375-9601(03)01144-7
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A U(3) <----> O(4) transitional description of diatomic molecules in the U(4) vibron model is considered. The analysis includes the U(3) and O(4) limits of the theory. Applications to vibrational-like band-heads of several diatomic molecules indicate that there are significant deviations from the O(4) limit of the theory. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:84 / 90
页数:7
相关论文
共 9 条
[1]  
Huber KP, 1979, MOL SPECTRA MOL STRU, DOI [10.1007/978-1-4757-0961-2_2, DOI 10.1007/978-1-4757-0961-2_2]
[2]   ALGEBRAIC APPROACH TO MOLECULAR ROTATION-VIBRATION SPECTRA .1. DIATOMIC-MOLECULES [J].
IACHELLO, F ;
LEVINE, RD .
JOURNAL OF CHEMICAL PHYSICS, 1982, 77 (06) :3046-3055
[3]   ALGEBRAIC METHODS FOR MOLECULAR ROTATION-VIBRATION SPECTRA [J].
IACHELLO, F .
CHEMICAL PHYSICS LETTERS, 1981, 78 (03) :581-585
[4]   Algebraic models in molecular spectroscopy [J].
Oss, S .
ADVANCES IN CHEMICAL PHYSICS, VOL XCIII, 1996, 93 :455-649
[5]   Algebraic solutions of an sl-boson system in the U(2l+1)⇆O(2l+2) transitional region [J].
Pan, F ;
Zhang, X ;
Draayer, JP .
JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 2002, 35 (33) :7173-7185
[6]   SPECTROSCOPY AND STRUCTURE OF THE ALKALI HYDRIDE DIATOMIC-MOLECULES AND THEIR IONS [J].
STWALLEY, WC ;
ZEMKE, WT ;
YANG, SC .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1991, 20 (01) :153-187
[7]  
STWALLEY WC, 1993, J PHYS CHEM REF DATA, V22, P89
[8]   A DYNAMIC ALGEBRA FOR ROTATION VIBRATION-SPECTRA OF COMPLEX-MOLECULES [J].
VANROOSMALEN, OS ;
DIEPERINK, AEL ;
IACHELLO, F .
CHEMICAL PHYSICS LETTERS, 1982, 85 (01) :32-36
[9]   ALGEBRAIC APPROACH TO MOLECULAR ROTATION-VIBRATION SPECTRA .2. TRIATOMIC-MOLECULES [J].
VANROOSMALEN, OS ;
IACHELLO, F ;
LEVINE, RD ;
DIEPERINK, AEL .
JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (06) :2515-2536