Syntheses and crystal structures of a tridentate enaminone and its copper complex

被引：41

作者：

Shi, YC ^{[1
]}

Sui, CX

Song, HB

Jian, PM

机构：

[1] Yangzhou Univ, Sch Chem, Yangzhou 225002, Peoples R China

[2] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 58卷 / 04期

关键词：

ferrocene; enaminone; ligand; copper; complex; X-ray crystallography;

D O I：

10.1080/00958970512331334278

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of ferrocenoylacetone [C5H5FeC5H4C(O)CH2C(O)CH3] and 2-aminoethanol yields a new ferrocene-containing ligand (H2L) that exists in the form of an enaminone formulated as [C5H5FeC5H4C(O)CH=C(NHCH2CH2OH)CH3]. Reaction of the enaminone H2L with copper acetate affords complex 1. X-ray crystallography of 1 reveals that it has a tetrameric structure composed of four CuL subunits linked by bridging alkoxide oxygen atoms in which the enaminone acts as a dianionic tridentate ligand and each of the four copper atoms is in a distorted square-pyramidal coordination environment.

引用

页码：363 / 371

页数：9

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