Platinum(IV) Complexes with Chelating N-Heterocyclic Carbene Ligands

被引：39
|
作者：
Meyer, Dirk [1 ]
Ahrens, Sebastian [1 ]
Strassner, Thomas [1 ]
机构：
[1] Tech Univ Dresden, D-01062 Dresden, Germany
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 15期
关键词：
STRUCTURAL-CHARACTERIZATION; OXIDATIVE ADDITION; PHOTOPHYSICAL PROPERTIES; CHLORIDE COMPLEXES; CRYSTAL-STRUCTURE; PT(II) COMPLEXES; PALLADIUM; NHC; ACTIVATION; CHEMISTRY;
D O I：
10.1021/om100488s
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Platinum(II) complexes with one or two chelatmg bis(NHC) ligands have been oxidized by bromine as well as iodobenzene dichloride to provide the corresponding platinum(IV) carbene complexes in good yields under very mild reaction conditions. All compounds have been fully characterized by H-1 and C-13 NMR spectroscopy and in three cases also by solid-state structures The NMR spectra of the novel Pt(IV) complexes show significantly shifted signals compared to their Pt(II) precursor complexes.
引用
收藏
页码：3392 / 3396
页数：5
相关论文
共 50 条
  • [1] Photofunctional Platinum Complexes Featuring N-heterocyclic Carbene-Based Pincer Ligands
    Lin, Wan-Jung
    Naziruddin, Abbas Raja
    Chen, Yu-Hsuan
    Sun, Bian-Jian
    Chang, A. Hsiu Hwa
    Wang, Wen-Jwu
    Hwang, Wen-Shu
    CHEMISTRY-AN ASIAN JOURNAL, 2015, 10 (03) : 728 - 739
  • [2] Methylpalladium complexes with pyrimidine-functionalized N-heterocyclic carbene ligands
    Meyer, Dirk
    Strassner, Thomas
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2016, 12 : 1557 - 1565
  • [3] Platinum(IV) N-heterocyclic carbene complexes: their synthesis, characterisation and cytotoxic activity
    Bouche, M.
    Dahm, G.
    Wantz, M.
    Fournel, S.
    Achard, T.
    Bellemin-Laponnaz, S.
    DALTON TRANSACTIONS, 2016, 45 (28) : 11362 - 11368
  • [4] Synthesis, characterization, and photophysical properties of cyclometalated N-Heterocyclic carbene Platinum(II) complexes
    Mastrocinque, Francesco
    Anderson, Craig M.
    Elkafas, Adel M.
    Ballard, Isabel V.
    Tanski, Joseph M.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2019, 880 : 98 - 107
  • [5] Synthesis and characterization of palladacyclopentadiene complexes with N-heterocyclic carbene ligands
    Canovese, Luciano
    Santo, Claudio
    Scattolin, Thomas
    Visentin, Fabiano
    Bertolasi, Valerio
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2015, 794 : 288 - 300
  • [6] An overview of anticancer platinum N-heterocyclic carbene complexes
    Zhao, Sai
    Yang, Zhibing
    Jiang, Guizhi
    Huang, Sheng
    Bian, Mianli
    Lu, Yunlong
    Liu, Wukun
    COORDINATION CHEMISTRY REVIEWS, 2021, 449
  • [7] Cobalt-platinum heterometallic clusters containing N-heterocyclic carbene ligands
    Chor, Bo Yang
    Koh, Wei Xiang
    Ganguly, Rakesh
    Li, Yongxin
    Chen, Luwei
    Raja, Robert
    Leong, Weng Kee
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 849-850 : 48 - 53
  • [8] Facile Hydrolysis of Nickel(II) Complexes with N-Heterocyclic Carbene Ligands
    Astakhov, Alexander V.
    Khazipov, Oleg V.
    Degtyareva, Evgeniya S.
    Khrustalev, Victor N.
    Chernyshev, Victor M.
    Ananikov, Valentine P.
    ORGANOMETALLICS, 2015, 34 (24) : 5759 - 5766
  • [9] Platinum(II) N-heterocyclic carbene complexes: coordination and cyclometallation
    Petretto, Giacomo L.
    Wang, Miao
    Zucca, Antonio
    Rourke, Jonathan P.
    DALTON TRANSACTIONS, 2010, 39 (33) : 7822 - 7825
  • [10] Synthesis of palladium(0) and -(II) complexes with chelating bis(N-heterocyclic carbene) ligands and their application in semihydrogenation
    Sluijter, Soraya N.
    Warsink, Stefan
    Lutz, Martin
    Elsevier, Cornelis J.
    DALTON TRANSACTIONS, 2013, 42 (20) : 7365 - 7372
12345