Investigation of Adsorption and Inhibitive Effect of Expired Helicure Drug on Mild Steel Corrosion in Hydrochloric Acid Solution

被引:7
作者
Al-Nami, Samar Y. [1 ]
机构
[1] King Khalid Univ, Sci Coll Girls, Chem Dept, Abha, Saudi Arabia
关键词
Acid corrosion; Mild steel; Expired Helicure drug; SEM; AFM; FTIR; SKULL BASE OSTEOMYELITIS; AMMONIUM-CHLORIDE; COPPER CORROSION; SURFACTANTS; EFFICIENCY; DIAGNOSIS; IRON; SCINTIGRAPHY; ALUMINUM; ABSENCE;
D O I
10.20964/2020.03.34
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The inhibiting impact of expired Helicure drug (EHD) on the dissolution of mild steel (MS) in 1 M HCl was evaluated using weight loss (WL) and electrochemical methods. The outcome data displayed that this drug was adsorbed physically on MS surface following Langmuir isotherm. Some thermodynamic factors computed and discussed. The obtained data designated that the protection efficiency (PE) improved by raising the concentrations of the drug and lowered by raising the temperature of the medium. The maximum protection efficiency 85.8% was detected in the existence of 300 ppm EHD (in case of polarization). The analysis of MS surface are performed by utilizing scanning electron microscope (SEM), Fourier transform Infrared spectroscopy (FTIR) and atomic force microscopy (AFM) tests. All obtained results from different techniques are almost similar.
引用
收藏
页码:2685 / 2699
页数:15
相关论文
共 48 条
[1]   Corrosion inhibition of aluminum by 1,1(lauryl amido)propyl ammonium chloride in HCl solution [J].
Abd El Rehim, SS ;
Hassan, HH ;
Amin, MA .
MATERIALS CHEMISTRY AND PHYSICS, 2001, 70 (01) :64-72
[2]  
Al-Azzawi A. M., 2016, IJRPC, V6, P3912
[3]   Effect of octylphenol polyethylene oxide on the corrosion inhibition of steel in 0.5 M H2SO4 [J].
Algaber, AS ;
El-Nemma, EM ;
Saleh, MM .
MATERIALS CHEMISTRY AND PHYSICS, 2004, 86 (01) :26-32
[4]   Benzimidazole and its derivatives as corrosion inhibitors for mild steel in 1M HCl solution [J].
Aljourani, J. ;
Raeissi, K. ;
Golozar, M. A. .
CORROSION SCIENCE, 2009, 51 (08) :1836-1843
[5]   Inhibition effect of newly synthesized heterocyclic organic molecules on corrosion of steel in alkaline medium containing chloride [J].
Ameer, M. A. ;
Fekry, A. M. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (20) :11387-11396
[6]  
Ameh P.O., 2015, J HETEROCYCLICS, V1, P2
[7]   The substituted 1,3,4-oxadiazoles: a new class of corrosion inhibitors of mild steel in acidic media [J].
Bentiss, F ;
Traisnel, M ;
Lagrenee, M .
CORROSION SCIENCE, 2000, 42 (01) :127-146
[8]   Aluminium corrosion in hydrochloric acid solutions and the effect of some organic inhibitors [J].
Branzoi, V ;
Golgovici, F ;
Branzoi, F .
MATERIALS CHEMISTRY AND PHYSICS, 2003, 78 (01) :122-131
[9]   Thiophene substituted dihydropyridines [J].
Caignan, GA ;
Metcalf, SK ;
Holt, EM .
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2000, 30 (06) :415-422
[10]  
Christopher M.A.B., 1994, CORROS SCI, V36, P9153