Recent progress in conversion reaction metal oxide anodes for Li-ion batteries

被引：293
作者：
Cao, Kangzhe [1 ]
Jin, Ting [1 ]
Yang, Li [1 ]
Jiao, Lifang [1 ,2 ]
机构：
[1] Nankai Univ, Coll Chem, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
来源：
MATERIALS CHEMISTRY FRONTIERS | 2017年 / 1卷 / 11期
基金：
中国国家自然科学基金;
关键词：
ENHANCED LITHIUM-STORAGE; HIGH-PERFORMANCE ANODE; REDUCED GRAPHENE OXIDE; HIGH-RATE-CAPABILITY; LONG-CYCLE-LIFE; LARGE-SCALE SYNTHESIS; ONE-STEP SYNTHESIS; ADVANCED ELECTRODE MATERIALS; ATOMIC LAYER DEPOSITION; SHELL NANOWIRE ARRAYS;
D O I：
10.1039/c7qm00175d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transition metal oxides (TMOs) based on conversion reactions are attractive candidate anode materials for lithium-ion batteries (LIBs) because of their high theoretical capacity and safety characteristics. In this review, we have summarized recent progress in the rational design and efficient synthesis of TMOs with controllable morphologies, compositions, and micro-/nanostructures, along with their Li storage behaviors. Single metal oxides of manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), ruthenium (Ru), chromium (Cr), molybdenum (Mo), and tungsten (W) and their common binary metal oxides have been discussed in this review. Finally, the less well-known merits of conversion reactions are put forward, and the design of metal oxide electrodes making full use of these merits has been proposed.
引用
收藏
页码：2213 / 2242
页数：30
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