Rapid phosphorus-nitrogen bond cleavage in bis(diphenylphosphino)amine.: Synthesis, X-ray structure and electrochemical characterization of [Ni2(μ2-Ph2P) (μ2-Ph2PNHPPh)2(CNR)2]X, R = Me, n-Bu, xylyl; X = Cl, I, BPh4 binuclear Ni(I) complexes

被引：5

作者：

Simón-Manso, E ^{[1
]}

Kubiak, CP ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 08期

关键词：

phosphorus nitrogen bond cleavage; nickel complexes; phosphido; dppa;

D O I：

10.1016/S1387-7003(03)00206-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ni(II) reacts with Ni(0) complexes in toluene solution to yield diamagnetic phosphido-bridging Ni(I)-Ni(I) complexes of the type Ni-2(mu(2)-PPh2)(CNR)(2)(mu(2)-dppa)(2). The great thermodynamic stability of these complexes is discussed on the light of their electrochemical properties. The X-ray crystal structure of the complexes Ni-2(mu(2)-PPh2)(CNR)(2)(mu(2)-dppa)(2), R = n-Bu, Xylyl is also presented. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：1096 / 1098

页数：3

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