On the electronic character of oxygen-transfer reactions

被引：32
作者：
Deubel, DV
Frenking, G
Senn, HM
Sundermeyer, J
机构：
[1] Univ Marburg, Fachbereich Chem, D-35035 Marburg, Germany
[2] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
[3] Swiss Fed Inst Technol, ETH Zentrum, Inorgan Chem Lab, CH-8092 Zurich, Switzerland
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 24期
关键词：
D O I：
10.1039/b006280o
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Charge Decomposition Analysis (CDA) applied to transition states of ethylene epoxidation is a quantum-chemical probe for the electronic character of oxygen-transfer reactions.
引用
收藏
页码：2469 / 2470
页数：2
相关论文
共 36 条
[1]   Thianthrene 5-oxide as a mechanistic probe in oxygen transfer reactions: The case of carbonyl oxides versus dioxiranes revisited [J].
Adam, W ;
Golsch, D ;
Gorth, FC .
CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (03) :255-258
[2]   Probing for electronic and steric effects in the peracid oxidation of thianthrene 5-oxide [J].
Adam, W ;
Golsch, D .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (01) :115-119
[3]   Titanium-catalysed oxidation of thianthrene 5-oxide in heterogeneous (zeolites) versus homogeneous media:: electrophilic versus template-mediated oxygen transfer [J].
Adam, W ;
Mitchell, CM ;
Saha-Möller, CR ;
Selvam, T ;
Weichold, O .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 154 (1-2) :251-255
[4]  
ALALJOUNI AM, J ORG CHEM
[5]  
ALALJOUNI AM, J AM CHEM SOC
[6]  
[Anonymous], ANGEW CHEM
[7]  
[Anonymous], ANGEW CHEM
[8]   KINETIC STUDIES ON OLEFIN EPOXIDATION BY PEROXO MOLYBDENUM COMPLEX (M0O(O2)2HMPT) [J].
ARAKAWA, H ;
MOROOKA, Y ;
OZAKI, A .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1974, 47 (12) :2958-2961
[9]   Transition state stereoelectronics in alkene epoxidations by fluorinated dioxiranes [J].
Armstrong, A ;
Washington, I ;
Houk, KN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (26) :6297-6298
[10]   TRANSITION STRUCTURE FOR THE EPOXIDATION OF ALKENES WITH PEROXY ACIDS - A THEORETICAL-STUDY [J].
BACH, RD ;
OWENSBY, AL ;
GONZALEZ, C ;
SCHLEGEL, HB ;
MCDOUALL, JJW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (06) :2338-2339
1234