Microwave synthesis and gas sorption of calcium and strontium metal-organic frameworks with high thermal stability

被引：65
作者：
Yeh, Chun-Ting [1 ]
Lin, Wei-Cheng [1 ]
Lo, Sheng-Han [1 ]
Kao, Ching-Che [1 ]
Lin, Chia-Her [1 ]
Yang, Chun-Chuen [2 ]
机构：
[1] Chung Yuan Christian Univ, Dept Chem, Chungli 32023, Taiwan
[2] Chung Yuan Christian Univ, Dept Phys, Chungli 32023, Taiwan
来源：
CRYSTENGCOMM | 2012年 / 14卷 / 04期
关键词：
CARBON-DIOXIDE CAPTURE; HYBRID POROUS SOLIDS; COORDINATION POLYMER; TRIPODAL LIGAND; CHEMISTRY; STORAGE; CHANNEL; DESIGN; LAYERS;
D O I：
10.1039/c2ce05875h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new calcium and strontium metal-organic frameworks [Ca(SBA)] (CYCU-1) and [Sr(SBA)] (CYCU-2) were prepared by microwave-assisted reactions. Both rigid frameworks are thermally stable up to about 450 degrees C. As verified by N-2, CO2, and H-2 sorption measurements, the thermally activated CYCU-1 and CYCU-2 exhibit significant microporosity.
引用
收藏
页码：1219 / 1222
页数：4
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