Cross-coupling reactions by cooperative Pd/Cu or Ni/Cu catalysis based on the catalytic generation of organocopper nucleophiles

被引：26

作者：

Semba, Kazuhiko ^{[1
]}

Nakao, Yoshiaki ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Nishikyo Ku, Kyoto 6158510, Japan

来源：

TETRAHEDRON | 2019年 / 75卷 / 06期

关键词：

Cooperative catalysis; Cross-coupling; Palladium; Nickel; Copper; ANTI-MARKOVNIKOV OXIDATION; DUAL CATALYSIS; ENANTIOSELECTIVE ARYLBORATION; STEREOSELECTIVE-SYNTHESIS; SONOGASHIRA REACTIONS; ALKYNYLZINC REAGENTS; SELECTIVE SYNTHESIS; ALLYLIC ALKYLATION; INTERNAL ALKYNES; ROOM-TEMPERATURE;

D O I：

10.1016/j.tet.2018.12.013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this review, cross-coupling reactions by cooperative Pd/Cu or Ni/Cu catalysis based on catalytically generated organocopper nucleophiles are summarized. Compared to conventional methods based on the use of stoichiometric amounts of pre-synthesized organometallic reagents, these methods are powerful tools for the alkynylation, arylation, alkenylation, and alkylation of organic electrophiles, especially as they can be carried out in a highly step-economical manner with readily available starting materials based on simple arenes, carboxylic acids, alkenes, and alkynes as pre-nucleophiles. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：709 / 719

页数：11

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