In situ synthesis, X-ray structure, fluorescence and theoretical investigations of [Cu2Cl4][(C2H5)2-4,4′-bipyridine]

被引：2

作者：

Chen, Wen-Tong ^{[1
]}

Liu, Dong-Sheng ^{[1
]}

Luo, Zhi-Gang ^{[1
]}

Chen, Hua-Long ^{[1
]}

Liu, Jiu-Hui ^{[1
]}

机构：

[1] Jinggangshan Univ, Sch Chem & Chem Engn, Jiangxi Prov Key Lab Coordinat Chem, Inst Appl Chem, Jian 343009, Jiangxi, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2011年 / 08期

关键词：

crystal structure; solvothermal reaction; in situ; bipyridine; fluorescence; CRYSTAL-STRUCTURE; PHOTOLUMINESCENCE; COMPLEXES; CATION; LIGAND; ANION;

D O I：

10.3184/174751911X13133111770286

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel N,N'-diethyl-4,4'-bipyridine copper complex, [Cu2Cl4][(C2H5)(2)-4,4'-bipyridine] (1), has been obtained in situ through a solvothermal reaction and structurally characterised by X-ray diffraction. Complex 1 comprises discrete Cu2Cl4 moieties and (C2H5)(2)-4,4'-bipyridine molecules interlinked via hydrogen bonding interactions to give a three-dimensional supramolecular open framework. Photoluminescent study shows that the complex exhibits an emission in the green region. Theoretical study reveals that the emission is attributed to the pi ->pi* charge-transfer interaction of the (C2H5)(2)-4,4'-bipyridine moieties.

引用

页码：491 / 493

页数：3

共 17 条

[1] ANION DESIGN BY CHOICE OF CATION - ISOLATION OF A DINUCLEAR CHLOROCUPRATE(I) ANION CONTAINING TRIGONALLY COORDINATED COPPER(I) USING THE TETRAETHYLPHOSPHONIUM CATION [J].

ANDERSSON, S ;

HAKANSSON, M ;

JAGNER, S .

INORGANICA CHIMICA ACTA, 1993, 209 (02) :195-199

[2]

[Anonymous], 2002, CRYSTALCLEAR VERS 1

[3] X-RAY CRYSTAL-STRUCTURE OF BIS(N,N'-ETHYLENE-BIS-(SALICYLIDENEIMINATO)-OXOVANADIUM(V)) DI-MU-CHLORODICOPPER(I) CHLORIDE, A COMPOUND WITH A 3-COORDINATE COPPER(I) CHLORIDE [J].

BANCI, L ;

BENCINI, A ;

DEI, A ;

GATTESCHI, D .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 84 (01) :L11-L12

[4]

BEGLEY MJ, 1988, J CHEM RES, V2, P101

[5]

BEGLEY MJ, 1986, J CHEM RES, V172, P1501

[6] In situ formation of heterobimetallic salen complexes containing titanium and/or vanadium ions [J].

Belokon, Yuri N. ;

Clegg, William ;

Harrington, Ross W. ;

North, Michael ;

Young, Carl .

INORGANIC CHEMISTRY, 2008, 47 (09) :3801-3814

[7] Metal-assisted in situ formation of a tridentate acetylacetone ligand for complexation of fac-Re(CO)3+ for radiopharmaceutical applications [J].

Benny, Paul D. ;

Fugate, Glenn A. ;

Barden, Adam O. ;

Morley, Jennifer E. ;

Silva-Lopez, Elsa ;

Twamley, Brendan .

INORGANIC CHEMISTRY, 2008, 47 (07) :2240-2242

[8]

BIGOLI F, 1990, J CHEM RES, V11, P1712

[9] Synthesis, Structure, Photoluminescence and Theoretical Study of {(N,N′-Dimethyl-4,4′-bipyridinium)[Cd2(μ2-Cl)4Cl2]}n with N,N′-Dimethyl-4,4′-bipyridinium Generated in Situ [J].

Chen, W. ;

Yao, Z. ;

Ying, S. ;

Liu, D. ;

Liu, J. .

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2010, 7 (01) :180-184

[10] Synthesis, structure and photoluminescence of [N-ethyl-4,4′-bipyridinium][CdBr4] with N-ethyl-4,4′-bipyridinium generated in situ [J].

Chen, Wentong ;

Yao, Zhongliang ;

Huang, Jinshun ;

Liu, Dongsheng ;

Ying, Shaoming ;

Liu, Jiuhui .

JOURNAL OF CHEMICAL RESEARCH, 2010, (11) :616-618

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