Synthesis and characterisation of polymeric manganese and zinc 5-hydroxyisophthalates

被引：43
作者：
Plater, MJ
Foreman, MR
Howie, RA
Skakle, JMS
McWilliam, SA
Coronado, E
Gómez-García, CJ
机构：
[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland
[2] Univ Valencia, Inst Ciencia Mol, E-46100 Burjassot, Spain
来源：
POLYHEDRON | 2001年 / 20卷 / 18期
关键词：
manganese; hydrothermal; co-ordination polymer;
D O I：
10.1016/S0277-5387(01)00804-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystallisation of 5-hydroxyisophthalic acid with divalent Mn or with Mn or Zn and either 2,2-bipyridine (2,2-bipy) or pyridine-2-(1H-pyrazol-3-yl) gave solids of composition [Mn(C8H4O5)(H2O)(3)]. 2H(2)O (1), [Mn(C8H4O5)(2,2 ' -bipy)].H2O (2), [Mn-2(C8H4O5)(2)(C8H7N3)(2)].H2O (3) and [Zn(C8H4O5)(2,2 ' -bipy)] (4). Each compound has 1D co-ordinative chains that are connected by hydrogen bonds. Compounds 2-4 contain M2C2O4 rings with pseudo-chair geometries. The Mn atoms in 2 are coupled antiferromagnetically. (C) 2001 Elsevier Science Ltd. All rights reserved.
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收藏
页码：2293 / 2303
页数：11
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