Air- and water-stable catalysts for hydroamination/cyclization. Synthesis and application of CCC-NHC pincer complexes of Rh and Ir

被引：148

作者：

Bauer, Eike B. ^{[2
]}

Andavan, G. T. Senthil ^{[2
]}

Hollis, T. Keith ^{[1
,2
]}

Rubio, Ramel J. ^{[2
]}

Cho, Joon ^{[1
,2
]}

Kuchenbeiser, Glenn R. ^{[2
]}

Helgert, Theodore R. ^{[1
]}

Letko, Christopher S. ^{[2
]}

Tham, Fook S. ^{[2
]}

机构：

[1] Univ Mississippi, Dept Chem & Biochem, University, MS 38677 USA

[2] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 06期

关键词：

D O I：

10.1021/ol8000766

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The scope of CCC-NHC pincer complex synthetic methodology by metalation/transmetalation has been extended to Ir. Structural characterization revealed that it is isomorphous with the Rh complex. Both Rh and Ir complexes are efficient catalysts for the hydroamination/cyclization of secondary amines in the presence of air and/or water.

引用

页码：1175 / 1178

页数：4

共 53 条

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