Gold Catalysts for the Selective Oxidation of Biomass-Derived Products

被引:52
作者
Cattaneo, Stefano [1 ]
Stucchi, Marta [1 ]
Villa, Alberto [1 ]
Prati, Laura [1 ]
机构
[1] Univ Milan, Dipartimento Chim, Via Golgi 19, I-20133 Milan, Italy
关键词
Gold; glucose oxidation; glycerol oxidation; HMF oxidation; biomass transformation; LIQUID-PHASE OXIDATION; BASE-FREE OXIDATION; BIMETALLIC GOLD/PALLADIUM CATALYSTS; FREE AEROBIC OXIDATION; LONG-TERM STABILITY; GLUCOSE-OXIDATION; BIODIESEL PRODUCTION; GLYCEROL OXIDATION; 2,5-FURANDICARBOXYLIC ACID; MOLECULAR-OXYGEN;
D O I
10.1002/cctc.201801243
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Biomass constitutes a renewable source for new chemical platforms. Among other processes the catalytic ones represent a green alternative when active and selective catalysts can be developed. In this paper, applications of gold and gold-based catalysts have been reviewed in the field of the selective oxidations. Indeed, from the discovery of the peculiarity of gold as catalytic material, the liquid phase oxidations have been differently viewed. Three important biomass-derived molecules, namely glucose, hydroxymethyl furfural (HMF) and glycerol have been considered as precursors for products of industrial interest where gold catalysts have played an important role. This review starts from the research on monometallic gold catalysts which have been explored initially and then look at gold as modifier of other metal catalyst. This latter field is still in evolution and probably needs to be look at in the future.
引用
收藏
页码:309 / 323
页数:15
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