catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ2N:N′] pyridine-3,5-dicarboxylate trihydrate]

被引：0

作者：

Zhu, Xian-Dong ^{[1
]}

机构：

[1] Anhui Polytech Univ, Coll Biol & Chem Engn, Wuhu 241000, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

D O I：

10.1107/S1600536811023816

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title compound, {[Co(C10H8N2)(H2O)(4)](C7H3NO4)center dot 3H(2)O}(n), consists of Co-II polymeric complex cations, uncoordinated pyridine-3,5-dicarboxylate anions and lattice water molecules. The Co-II cation is coordinated by two N atoms from two 4,4 '-bipyridine ligands and four water molecules in a distorted octahedral geometry. The 4,4 '-bipyridine ligands bridge Co cations, forming a polymeric chain running along the b axis. The two pyridine rings of the 4,4 '-biyridine are twisted to each other by a dihedral angle of 8.95 (9)degrees. Extensive O-H center dot center dot center dot O hydrogen bonding network is present in the crystal structure.

引用

页码：M970 / U1391

页数：11

共 50 条

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