catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ2N:N′] pyridine-3,5-dicarboxylate trihydrate]

被引：0
|
作者：
Zhu, Xian-Dong [1 ]
机构：
[1] Anhui Polytech Univ, Coll Biol & Chem Engn, Wuhu 241000, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811023816
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title compound, {[Co(C10H8N2)(H2O)(4)](C7H3NO4)center dot 3H(2)O}(n), consists of Co-II polymeric complex cations, uncoordinated pyridine-3,5-dicarboxylate anions and lattice water molecules. The Co-II cation is coordinated by two N atoms from two 4,4 '-bipyridine ligands and four water molecules in a distorted octahedral geometry. The 4,4 '-bipyridine ligands bridge Co cations, forming a polymeric chain running along the b axis. The two pyridine rings of the 4,4 '-biyridine are twisted to each other by a dihedral angle of 8.95 (9)degrees. Extensive O-H center dot center dot center dot O hydrogen bonding network is present in the crystal structure.
引用
收藏
页码：M970 / U1391
页数：11
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