Niobic acid nanoparticle catalysts for the aqueous phase transformation of glucose and fructose to 5-hydroxymethylfurfural

被引：29
|
作者：
Reche, Mariano Tapia [1 ]
Osatiashtiani, Amin [1 ]
Durndell, Lee J. [1 ]
Isaacs, Mark A. [1 ]
Silva, Angela [2 ]
Lee, Adam F. [1 ]
Wilson, Karen [1 ]
机构：
[1] Aston Univ, European Bioenergy Res Inst, Birmingham B4 7ET, W Midlands, England
[2] Univ Fed Parana UFPR, Dept Quim, Lab Bioinorgan & Catalise, CP 19081, BR-81531990 Curitiba, Parana, Brazil
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2016年 / 6卷 / 19期
基金：
英国工程与自然科学研究理事会;
关键词：
CONVERSION; DEHYDRATION; OXIDE; BIOMASS; SUCROSE; SILICA; WATER; HMF; EFFICIENT; SITES;
D O I：
10.1039/c6cy01129b
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A family of bulk and SBA-15 supported peroxo niobic acid sols were prepared by peptisation of niobic acid precipitates with H2O2 as heterogeneous catalysts for aqueous phase glucose and fructose conversion to 5-hydroxymethylfurfural (5-HMF). Niobic acid nanoparticles possess a high density of Bronsted and Lewis acid sites, conferring good activity towards glucose and fructose conversion, albeit with modest 5-HMF yields under mild reaction conditions (100 degrees C). Thermally-induced niobia crystallisation suppresses solid acidity and activity. Nanoparticulate niobic acid dispersed over SBA-15 exhibits pure Bronsted acidity and an enhanced Turnover Frequency for fructose dehydration.
引用
收藏
页码：7334 / 7341
页数：8
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