Synthesis of Stable Thiazole-Linked Covalent Organic Frameworks via a Multicomponent Reaction

被引：226

作者：

Wang, Kewei ^{[1
,2
,3
,4
]}

Jia, Zhifang ^{[1
,2
,3
,4
]}

Bai, Yang ^{[1
,2
]}

Wang, Xue ^{[1
,2
,3
]}

Hodgkiss, Sophie E. ^{[1
,2
,3
]}

Chen, Linjiang ^{[1
,2
,3
]}

Chong, Samantha Y. ^{[1
,2
]}

Wang, Xiaoyan ^{[1
,2
]}

Yang, Haofan ^{[1
,2
,3
]}

Xu, Yongjie ^{[1
,2
,3
]}

Feng, Feng ^{[4
]}

Ward, John W. ^{[1
,2
,3
]}

Cooper, Andrew, I ^{[1
,2
,3
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

[2] Univ Liverpool, Mat Innovat Factory, Liverpool L69 7ZD, Merseyside, England

[3] Univ Liverpool, Leverhulme Res Ctr Funct Mat Design, Liverpool L69 7ZD, Merseyside, England

[4] Shanxi Datong Univ, Dept Chem & Chem Engn, Datong 037009, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2020年 / 142卷 / 25期

基金：

中国国家自然科学基金;

关键词：

HIGH-PERFORMANCE; CRYSTALLINE; EFFICIENT; POLYMER; EVOLUTION; LINKAGES;

D O I：

10.1021/jacs.0c03418

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of robust synthetic routes to stable covalent organic frameworks (COFs) is important to broaden the range of applications for these materials. We report here a simple and efficient three-component assembly reaction between readily available aldehydes, amines, and elemental sulfur via a C-H functionalization and oxidative annulation under transition-metal-free conditions. Five thiazole-linked COFs (TZ-COFs) were synthesized using this method. These materials showed high levels of crystallinity, high specific surface areas, and excellent physicochemical stability. The photocatalytic applications of TZ-COFs were investigated, and TZ-COF-4 gave high sacrificial hydrogen evolution rates from water (up to 4296 mu mol h(-1) g(-1) under visible light irradiation) coupled with high stability and recyclability, with sustained hydrogen evolution for 50 h.

引用

页码：11131 / 11138

页数：8

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