Radiation effects in alpha-doped UO2

UO2 samples doped with the strong alpha-emitter Pu-238 were periodically characterised to study the potential effects of alpha-self-irradiation on spent nuclear fuel during storage. The degradation of the thermal properties and microstructure of the samples were monitored using the Laser Flash technique (LAF), X-Ray Diffraction (XRD), and Scanning and Transmission Electron Microscopy (SEM, TEM). The thermal conductivity decreased with a nonlinear behaviour as a function of the alpha-dose. Three clearly different stages in the thermal conductivity degradation could be detected, and saturation was reached at relatively low doses (0.035 dpa). In combination with analyses of the microstrain measured by XRD, and TEM images, these three phases could be attributed to three stages of radiation-induced defect generation and clustering. SEM inspection showed the thermal conductivity degradation cannot be due to loss of integrity or grain boundary opening. The radiation damage produced resulted in the formation of dislocation loops as observed by TEM.