Self-assembly of ligand-bridged molecular rectangles containing fac-Re(CO)3 corners

被引：127

作者：

Woessner, SM ^{[1
]}

Helms, JB ^{[1
]}

Shen, YB ^{[1
]}

Sullivan, BP ^{[1
]}

机构：

[1] Univ Wyoming, Dept Chem, Laramie, WY 82071 USA

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 21期

关键词：

D O I：

10.1021/ic9805168

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of molecular rectangles have been synthesized by self-assembly using Re(CO)(5)OTf, 4,4'-bipyridine and an alcohol or water. The rectangles have been characterized by elemental analysis as well as IR,H-1 NMR and UV-visible spectroscopies, and in one case cyclic voltammetry and an X-ray structure determination. These complexes are representatives of a new structural class of molecular parallelograms containing the unusual combination of carbon monoxide and alkoxide ligands around a Re(I) center.

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页码：5406 / +

页数：3

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