Two-Photon Responsive Metal Organic Framework

被引：189

作者：

Yu, Jiancan ^{[1
]}

Cui, Yuanjing ^{[1
]}

Wu, Chuan-De ^{[2
]}

Yang, Yu ^{[1
]}

Chen, Banglin ^{[1
,3
]}

Qian, Guodong ^{[1
]}

机构：

[1] Zhejiang Univ, Sch Mat Sci & Engn, Cyrus Tang Ctr Sensor Mat & Applicat, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China

[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

[3] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 12期

基金：

中国国家自然科学基金; 美国国家科学基金会; 中国博士后科学基金;

关键词：

CARBON-DIOXIDE CAPTURE; ENERGY-TRANSFER; DATA-STORAGE; EFFICIENT; 3D; DESIGN;

D O I：

10.1021/ja512552g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two-photon processing presents a facile means to tailor the properties of materials in three-dimensions. A two-photon responsive metal-organic framework (MOF) has been realized through the incorporation of a photoactive linker into a MOF via a multivariate strategy. The resulting MOF exhibits a significant one-photon and two-photon excited fluorescence change in response to UV light and infrared femtosecond laser, enabling spatial modulation of the fluorescence property of the MOF. It thus demonstrates the capacity of two-photon patterning and imaging inside the crystal, and the formation of three-dimensional two-photon excited fluorescent structure in a high resolution.

引用

页码：4026 / 4029

页数：4

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