Synthesis and spectral characterization of macrocyclic NiII complexes derived from various diamines, NiII perchlorate and 1,4-bis(2-carboxyaldehydephenoxy)butane

被引：44

作者：

Ilhan, Salih ^{[1
]}

Temel, Hamdi

Kilic, Ahmet

Tas, Esref

机构：

[1] Dicle Univ, Dept Chem, Fac Educ, TR-21280 Diyarbakir, Turkey

[2] Harran Univ, Dept Chem, Fac Art & Sci, TR-63100 Sanliurfa, Turkey

来源：

TRANSITION METAL CHEMISTRY | 2007年 / 32卷 / 08期

关键词：

D O I：

10.1007/s11243-007-0260-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Six new macrocyclic complexes were synthesized by reaction of 1,4-bis(2-carboxyaldehyde phenoxy)butane with various diamines. Then, their nickel(II) perchlorate complexes were synthesized by the template effect by reaction of 1,4-bis(2-carboxyaldehyde phenoxy)butane, Ni(ClO4)(2) center dot 6H(2)O and various diamines. The metal-to-ligand ratio of Ni-II metal complexes was found to be 1:1. The compounds are coordinated to the central metal as tetradentate O2N2 ligands The Ni-II complexes are proposed to exhibit tetrahedral geometry. Ni-II metal complexes are 1:2 electrolytes as shown by their molar conductivities (Lambda(M)) in DMF (dimethyl formamide) at 10(-3) M. The structure of Ni-II metal complexes is proposed from elemental analysis, f.t.-i.r., u.v.-vis., magnetic susceptibility measurements, molar conductivity measurements and mass spectra.

引用

页码：1012 / 1017

页数：6

共 43 条

[1] METAL-ION SELECTIVITY BY MACROCYCLIC LIGANDS .3. THE INTERACTION OF MNII AND COII WITH PYRIDINYL-DERIVED N3O2 MACROCYCLES - X-RAY STRUCTURES OF ENDOMACROCYCLIC COMPLEXES OF MNII AND COII [J].

BAILEY, NA ;

FENTON, DE ;

KITCHEN, SJ ;

LILLEY, TH ;

WILLIAMS, MG ;

TASKER, PA ;

LEONG, AJ ;

LINDOY, LF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (11) :2989-2994

[2]

Barefield E. K., 1976, INORG SYNTH, V16, P220, DOI DOI 10.1002/9780470132470.CH58

[3] Modern spectroscopic techniques in the characterization of Schiff base macrocyclic ligand and its complexes with transition metals [J].

Chandra, S ;

Gupta, LK .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2005, 62 (1-3) :307-312

[4] Chromium(III), manganese(II), iron(III), cobalt(II), nickel(II) and copper(II) complexes with a pentadentate, 15-membered new macrocyclic ligand [J].

Chandra, S ;

Gupta, K .

TRANSITION METAL CHEMISTRY, 2002, 27 (02) :196-199

[5]

Chandra S., 2003, J SAUDI CHEM SOC, V7, P243

[6]

Chandra S., 2004, J SAUDI CHEM SOC, V8, P85

[7] Synthesis and properties of nickel(II) and copper(II) complexes of a di-N-acetamide tetraaza macrocycle [J].

Choi, KY ;

Lee, HH ;

Park, BB ;

Kim, JH ;

Kim, JW ;

Kim, MW ;

Ryu, JW ;

Suh, M ;

Suh, IH .

POLYHEDRON, 2001, 20 (15-16) :2003-2009

[8] SYNTHESIS AND ION BINDING OF SYNTHETIC MULTIDENTATE MACROCYCLIC-COMPOUNDS [J].

CHRISTENSEN, JJ ;

EATOUGH, DJ ;

IZATT, RM .

CHEMICAL REVIEWS, 1974, 74 (03) :351-384

[9]

CHRISTOPHER WG, 1982, J CHEM SOC DA, P2127

[10] SYNTHESIS OF A 13-MEMBERED TETRA-AZAMACROCYCLE EMPLOYING FORMALDEHYDE AND NITROALKANES DIRECTED BY METAL-IONS - CRYSTAL-STRUCTURES OF (12-METHYL-12-NITRO-1,4,7,10-TETRA-AZACYCLOTRIDECANE)COPPER(II) PERCHLORATE AND MU-CHLORO-1,1,1-TRICHLORO-2-(12-METHYL-12-NITRO-1,4,7,10-TETRA-AZACYCLOTRIDECANE)DICOPPER(II)2 [J].

COMBA, P ;

CURTIS, NF ;

LAWRANCE, GA ;

OLEARY, MA ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (02) :497-502

← 1 2 3 4 5 →