Achiral aromatic solvent-induced assembly of 3-D homochiral porous 3d-4f heterometallic-organic frameworks based on isonicotinic acid

被引：9

作者：

Jin, Hong-Guang ^{[1
,2
,3
]}

Hong, Xu-Jia ^{[1
,2
,3
]}

Tan, Hao-Chong ^{[1
,2
,3
]}

Wei, Qin ^{[1
,2
,3
]}

Lin, Xiao-Ming ^{[1
,2
,3
]}

Cai, Yue-Peng ^{[1
]}

机构：

[1] South China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China

[2] Key Lab Energy Convers & Energy Storage Mat Guang, Guangzhou 510006, Guangdong, Peoples R China

[3] Guangdong Prov Engn Technol Res Ctr Mat Energy Co, Guangzhou 510006, Guangdong, Peoples R China

来源：

CRYSTENGCOMM | 2017年 / 19卷 / 40期

关键词：

HETEROGENEOUS ASYMMETRIC CATALYSIS; CHIRAL-SYMMETRY-BREAKING; SPONTANEOUS RESOLUTION; COORDINATION POLYMER; ENANTIOSELECTIVE SEPARATION; MICROPOROUS FRAMEWORK; IONOTHERMAL SYNTHESIS; 3D ARCHITECTURES; BUILDING-BLOCKS; SINGLE-CRYSTAL;

D O I：

10.1039/c7ce01580a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Via induction of achiral aromatic solvents, two 3-D monochiral 3d-4f MOFs (1 and 2) from the ligand HIN without any chiral auxiliary are uncommonly constructed. The results show that the homochiral compounds 1 and 2 are enantiopure rather than exhibiting enantiomeric excess. Obviously, this work has brought major synthetic advancement in homochiral framework materials of great significance. © 2017 The Royal Society of Chemistry.

引用

页码：5956 / 5959

页数：4

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