The aurophilicity phenomenon: A decade of experimental findings, theoretical concepts and emerging applications

被引：514
作者：
Schmidbaur, H [1 ]
机构：
[1] Tech Univ Munich, Inst Anorgan Chem, D-85747 Garching, Germany
来源：
GOLD BULLETIN | 2000年 / 33卷 / 01期
关键词：
D O I：
10.1007/BF03215477
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The term 'aurophilicity' was introduced in 1989 to describe phenomena in the structural chemistry of gold which could not be readily rationalized by conventional concepts of chemical bonding. In the following decade the aurophilicity concept has been widely applied and supported by the results of many experimental as well as theoretical studies. It will be carried over into the new millennium as a continued incentive for investigations that will help in the understanding of the unique properties of gold.
引用
收藏
页码：3 / 10
页数：8
相关论文
共 109 条
[1]   Silver(I)-silver(I) interactions in the tetrameric silver thiolate phosphine complex [Ag4(SPh)4(PPh3)4] [J].
Ahmed, LS ;
Dilworth, JR ;
Miller, JR ;
Wheatley, N .
INORGANICA CHIMICA ACTA, 1998, 278 (02) :229-231
[2]  
Ahrens B, 1999, EUR J INORG CHEM, P1103
[3]   SYNTHESIS AND CRYSTAL-STRUCTURE OF CYANO(TRIMETHYLPHOSPHINE)GOLD(I) [J].
AHRLAND, S ;
AURIVILLIUS, B ;
DREISCH, K ;
NOREN, B ;
OSKARSSON, A .
ACTA CHEMICA SCANDINAVICA, 1992, 46 (03) :262-265
[4]   Synthesis and structural characterization of [NEt4][Fe3(μ3-O)(μ3-AUPPh3)(μ-CO)3(CO)6], the new [Au6(μ3-S)2(PPh3)6][Fe3(μ3-S)(μ-AuPPh3)(CO)9]2 and [Au6(μ-S)2(PPh3)6][Fe5(μ3-S)2(CO)14] ionic solids containing assemblages of cluster-cations and cluster-anions [J].
Albano, VG ;
Castellari, C ;
Femoni, C ;
Iapalucci, MC ;
Longoni, G ;
Monari, M ;
Rauccio, M ;
Zacchini, S .
INORGANICA CHIMICA ACTA, 1999, 291 (1-2) :372-379
[5]   PRIMARY AMINES AS NUCLEATION CENTERS FOR GOLD CLUSTERING, AND THE STRUCTURAL CHEMISTRY OF POLYGOLD AMMONIUM CATIONS [J].
ANGERMAIER, K ;
SCHMIDBAUR, H .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (04) :559-564
[6]   CRYSTAL-STRUCTURES OF CHLORO(TRIMETHYLPHOSPHINE)GOLD(I), CHLORO(TRI-(I)PROPYLPHOSPHINE)GOLD(2) AND BIS(TRIMETHYLPHOSPHINE)GOLD(I) CHLORIDE [J].
ANGERMAIER, K ;
ZELLER, E ;
SCHMIDBAUR, H .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 472 (1-2) :371-376
[7]   Preparation and structure of poly(gold)telluronium salts [J].
Angermaier, K ;
Schmidbaur, H .
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (06) :879-882
[8]   A NEW STRUCTURAL MOTIF OF GOLD CLUSTERING AT OXIDE CENTERS IN THE DICATION [AU6O2(PME3)6]2+ [J].
ANGERMAIER, K ;
SCHMIDBAUR, H .
INORGANIC CHEMISTRY, 1994, 33 (10) :2069-2071
[9]  
[Anonymous], 1989, GOLD BULL
[10]   SYNTHESES, STRUCTURES, AND SPECTROSCOPIC PROPERTIES OF GOLD(I) COMPLEXES OF 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE (TPA) - CORRELATION OF THE SUPRAMOLECULAR AU...AU INTERACTION AND PHOTOLUMINESCENCE FOR THE SPECIES (TPA)AUCL AND [(TPA-HCL)AUCL] [J].
ASSEFA, Z ;
MCBURNETT, BG ;
STAPLES, RJ ;
FACKLER, JP ;
ASSMANN, B ;
ANGERMAIER, K ;
SCHMIDBAUR, H .
INORGANIC CHEMISTRY, 1995, 34 (01) :75-83
12345678910