An enantiomerically pure dinuclear triple-stranded helicate:: X-ray structure, CD spectroscopy and DFT calculations

被引：27

作者：

Albrecht, M ^{[1
]}

Janser, I

Fleischhauer, J

Wang, YK

Raabe, G

Fröhlich, R

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany

[2] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

MENDELEEV COMMUNICATIONS | 2004年 / 14卷 / 06期

关键词：

D O I：

10.1070/MC2004v014n06ABEH002031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An enantiomerically pure dinuclear triple-stranded titanium(IV) helicate is formed from a dicatechol diimine ligand with an (R,R)-1,2-diaminocyclohexane spacer and its stereochemical features are elucidated by experimental and theoretical methods.

引用

页码：250 / 253

页数：4

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