Study on adsorption performance of conjugated microporous polymers for hydrogen and organic solvents: The role of pore volume

被引：50
作者：
Tan, Dazhi [2 ]
Fan, Wenjie [3 ]
Xiong, Wannan [2 ]
Sun, Hanxue [1 ]
Li, An [1 ]
Deng, Weiqiao [3 ]
Meng, Changgong [2 ]
机构：
[1] Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
[2] Dalian Univ Technol, Fac Chem Environm & Biol Sci & Technol, Expt Ctr Chem, Dalian 116024, Peoples R China
[3] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
来源：
EUROPEAN POLYMER JOURNAL | 2012年 / 48卷 / 04期
关键词：
Homocoupled conjugated microporous polymers; Pore volume; Monomer ratio; Oil/organic solvents; Hydrogen storage; SURFACE-AREA; NETWORKS SYNTHESIS; POROSITY;
D O I：
10.1016/j.eurpolymj.2012.01.012
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of homocoupled conjugated microporous polymers (HCMPs) were prepared by cross-coupling polymerization of 1,3,5-triethynylbenzene and 1,4-diethynylbenzene with various monomer molar ratios. Our results show that the molar ratio of monomers has a remarkable influence on the surface area, pore volume, and micropore volume of the as-synthesized HCMP samples. With the increase of molar ratio of 1,3,5-triethynylbenzene to 1,4-diethynylbenzene, the surface area and total pore volume increased while the micropore volume decreased for these HCMP samples. We also investigated the adsorption performance for hydrogen and organic solvents of these HCMP samples. Results obtained from experiments show that the increase of total pore volume (contributed from both mesopore and micropore) of HCMPs would lead to an increase in their adsorption abilities for organic solvents, while hydrogen sorption ability for HCMPs can only be improved by increasing their micropore volume, which may provide useful guidance for the rational design of novel HCMPs with different porosities as absorbent materials for oil/organic solvents or hydrogen storage systems. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：705 / 711
页数：7
相关论文
共 29 条
[1]   Functionalizing Porous Aromatic Frameworks with Polar Organic Groups for High-Capacity and Selective CO2 Separation: A Molecular Simulation Study [J].
Babarao, Ravichandar ;
Dai, Sheng ;
Jiang, De-en .
LANGMUIR, 2011, 27 (07) :3451-3460
[2]   Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area [J].
Ben, Teng ;
Ren, Hao ;
Ma, Shengqian ;
Cao, Dapeng ;
Lan, Jianhui ;
Jing, Xiaofei ;
Wang, Wenchuan ;
Xu, Jun ;
Deng, Feng ;
Simmons, Jason M. ;
Qiu, Shilun ;
Zhu, Guangshan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) :9457-9460
[3]   Porous, crystalline, covalent organic frameworks [J].
Côté, AP ;
Benin, AI ;
Ockwig, NW ;
O'Keeffe, M ;
Matzger, AJ ;
Yaghi, OM .
SCIENCE, 2005, 310 (5751) :1166-1170
[4]   Ordered porous materials for emerging applications [J].
Davis, ME .
NATURE, 2002, 417 (6891) :813-821
[5]   Chemical tuning of CO2 sorption in robust nanoporous organic polymers [J].
Dawson, Robert ;
Adams, Dave J. ;
Cooper, Andrew I. .
CHEMICAL SCIENCE, 2011, 2 (06) :1173-1177
[6]   High Surface Area Conjugated Microporous Polymers: The Importance of Reaction Solvent Choice [J].
Dawson, Robert ;
Laybourn, Andrea ;
Khimyak, Yaroslav Z. ;
Adams, Dave J. ;
Cooper, Andrew I. .
MACROMOLECULES, 2010, 43 (20) :8524-8530
[7]   Functionalized Conjugated Microporous Polymers [J].
Dawson, Robert ;
Laybourn, Andrea ;
Clowes, Rob ;
Khimyak, Yaroslav Z. ;
Adams, Dave J. ;
Cooper, Andrew I. .
MACROMOLECULES, 2009, 42 (22) :8809-8816
[8]   Troger's base-functionalised organic nanoporous polymer for heterogeneous catalysis [J].
Du, Xin ;
Sun, Yalei ;
Tan, Bien ;
Teng, Qingfeng ;
Yao, Xiaojun ;
Su, Chengyong ;
Wang, Wei .
CHEMICAL COMMUNICATIONS, 2010, 46 (06) :970-972
[9]   Designed synthesis of 3D covalent organic frameworks [J].
El-Kaderi, Hani M. ;
Hunt, Joseph R. ;
Mendoza-Cortes, Jose L. ;
Cote, Adrien P. ;
Taylor, Robert E. ;
O'Keeffe, Michael ;
Yaghi, Omar M. .
SCIENCE, 2007, 316 (5822) :268-272
[10]   Palladium Nanoparticle Incorporation in Conjugated Microporous Polymers by Supercritical Fluid Processing [J].
Hasell, Tom ;
Wood, Colin D. ;
Clowes, Rob ;
Jones, James T. A. ;
Khimyak, Yaroslav Z. ;
Adams, Dave J. ;
Cooper, Andrew I. .
CHEMISTRY OF MATERIALS, 2010, 22 (02) :557-564
123