Flour food waste derived activated carbon for high-performance supercapacitors

被引:49
作者
Zhan, Changzhen [1 ]
Yu, Xiaoliang [1 ]
Liang, Qinghua [1 ]
Liu, Wei [1 ]
Wang, Yanbo [3 ]
Lv, Ruitao [2 ]
Huang, Zheng-Hong [1 ,2 ]
Kang, Feiyu [2 ]
机构
[1] Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
[2] Tsinghua Univ, Sch Mat Sci & Engn, MOE, Key Lab Adv Mat, Beijing 100084, Peoples R China
[3] Renmin Univ China, High Sch, Beijing 100080, Peoples R China
基金
中国国家自然科学基金;
关键词
HIERARCHICAL POROUS CARBON; HIGH VOLUMETRIC PERFORMANCE; NITROGEN-DOPED GRAPHENE; ELECTRODE MATERIAL; MESOPOROUS CARBON; THERMAL-TREATMENT; WILLOW CATKINS; CAPACITANCE; BIOMASS; ENERGY;
D O I
10.1039/c6ra18056f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
It is of great importance to develop electrode materials at a low cost for constructing high-performance electrochemical energy storage systems. Herein, we employed flour food waste residue as a raw material to prepare porous carbon based supercapacitor electrodes through the carbonization and subsequent KOH activation process. The as-prepared biomass-derived activated carbon exhibits an interconnected porous network with numberous open micropores and appropriate mesopores. Meanwhile, its moderate total pore volume results in a high mass density of 0.86 g cm(-3). When used as supercapacitor electrodes in an aqueous solution of KOH (6 mol L-1), the porous carbon material shows a high specific capacitance (278 F g(-1), 241 F cm(-3)) and good cycling stability with 95% capacitance retention over 3000 cycles at a current density of 2 A g(-1). Furthermore, even at an ultrahigh current density of 100 A g(-1) (charge/discharge completed within 3 s), it still maintains a high specific capacitance of 142 F g(-1) (122 F cm(-3)).
引用
收藏
页码:89391 / 89396
页数:6
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