Redox active ligand and metal cooperation for C(sp2)-H oxidation: extension of the galactose oxidase mechanism in water-mediated amide formation

被引：6

作者：

Alaji, Zahra ^{[1
]}

Safaei, Elham ^{[2
]}

Yi, Hong ^{[3
]}

Cong, Hengjiang ^{[3
]}

Wojtczak, Andrzej ^{[4
]}

Lei, Aiwen ^{[3
]}

机构：

[1] IASBS, Zanjan 4513766731, Iran

[2] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran

[3] Wuhan Univ, IAS, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China

[4] Nicolaus Copernicus Univ, Fac Chem, PL-87100 Torun, Poland

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 43期

基金：

美国国家科学基金会;

关键词：

AEROBIC OXIDATION; PRIMARY ALCOHOLS; MODEL COMPLEXES; COPPER(II); ALDIMINE; CO; CU; GENERATION; REACTIVITY; MOIETY;

D O I：

10.1039/c8dt03477j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Redox interplay between a ligand and a metal can provide a profound driving force for the promotion of unprecedented reactions. This work presents an intriguing water-assisted oxidative transformation of imine to amide with no formal change in the metal oxidation state in the copper and nickel complexes of an aminophenol ligand versus a zinc analogue.

引用

收藏

页码：15293 / 15297

页数：5

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