Improved detection of Hg2+ in aqueous solution with high sensitivity and selectivity by using mercury-specific DNA, Sybr Green I and gold nanoparticles

被引:0
作者
Xu, Hui [1 ]
Gao, Shuli [1 ]
Chen, Jiannong [2 ]
Liu, Quanwen [1 ]
机构
[1] Ludong Univ, Sch Chem & Mat Sci, Yantai 264025, Peoples R China
[2] Ludong Univ, Dept Phys, Yantai 264025, Peoples R China
来源
ADVANCED MATERIALS, PTS 1-4 | 2011年 / 239-242卷
关键词
Sybr Green I; Hg2+; K+; Gold nanoparticle; ANODIC-STRIPPING VOLTAMMETRY; PLASMA-MASS SPECTROMETRY; TURN-ON; COLORIMETRIC DETECTION; CONJUGATED POLYMERS; ENERGY-TRANSFER; SOIL SAMPLES; FLUORESCENCE; ION; MOLECULES;
D O I
10.4028/www.scientific.net/AMR.239-242.934
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
We report a label-free, fast, fluorescence turn on assay for Hg2+ detecton by using mercury-specific DNA (MSD), Sybr Green I (SG) and gold nanoparticles (AuNPs). SG efficiently discriminates MSD and MSD/Hg2+ complex. The addition of gold nanoparticle decreases the background fluorescence signal further for MSD. The fluorescence intensity of MSD/Hg2+ complex keeps constant after addition of AuNPs. This property improves the signal-to-background ratio and decreases the detection limitation further. In addition, the method shows improved selectivity compared with that in the absence of AuNPs. This strategy could be applied to the detection of potassium ions and showed good generality.
引用
收藏
页码:934 / +
页数:3
相关论文
共 41 条
  • [1] Trace determination of mercury by anodic stripping voltammetry at the rotating gold electrode
    Bonfil, Y
    Brand, M
    Kirowa-Eisner, E
    [J]. ANALYTICA CHIMICA ACTA, 2000, 424 (01) : 65 - 76
  • [2] A novel fluorescent array for mercury (II) ion in aqueous solution with functionalized cadmium selenide nanoclusters
    Chen, Jinlong
    Gao, YingChun
    Xu, ZhiBing
    Wu, GenHua
    Chen, YouCun
    Zhu, ChangQing
    [J]. ANALYTICA CHIMICA ACTA, 2006, 577 (01) : 77 - 84
  • [3] Oligonucleotide-based fluorescence probe for sensitive and selective detection of mercury(II) in aqueous solution
    Chiang, Cheng-Kang
    Huang, Chih-Ching
    Liu, Chi-Wei
    Chang, Huan-Tsung
    [J]. ANALYTICAL CHEMISTRY, 2008, 80 (10) : 3716 - 3721
  • [4] Reversible colorimetric probes for mercury sensing
    Coronado, E
    Galán-Mascaros, JR
    Martí-Gastaldo, C
    Palomares, E
    Durrant, JR
    Vilar, R
    Gratzel, M
    Nazeeruddin, MK
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (35) : 12351 - 12356
  • [5] Signal ratio amplification via modulation of resonance energy transfer: Proof of principle in an emission ratiometric Hg(II) sensor
    Coskun, Ali
    Akkaya, Engin U.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (45) : 14474 - 14475
  • [6] Selective detection of mercury (II) ion using nonlinear optical properties of gold nanoparticles
    Darbha, Gopala Krishna
    Singh, Anant Kumar
    Rai, Uma Shanker
    Yu, Eugene
    Yu, Hongtao
    Ray, Paresh Chandra
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (25) : 8038 - 8043
  • [7] Energy flow and fluorescence near a small metal particle
    Das, PC
    Puri, A
    [J]. PHYSICAL REVIEW B, 2002, 65 (15): : 1554161 - 1554168
  • [8] Fluorescence quenching of dye molecules near gold nanoparticles:: Radiative and nonradiative effects -: art. no. 203002
    Dulkeith, E
    Morteani, AC
    Niedereichholz, T
    Klar, TA
    Feldmann, J
    Levi, SA
    van Veggel, FCJM
    Reinhoudt, DN
    Möller, M
    Gittins, DI
    [J]. PHYSICAL REVIEW LETTERS, 2002, 89 (20) : 203002 - 203002
  • [9] Gold nanoparticles quench fluorescence by phase induced radiative rate suppression
    Dulkeith, E
    Ringler, M
    Klar, TA
    Feldmann, J
    Javier, AM
    Parak, WJ
    [J]. NANO LETTERS, 2005, 5 (04) : 585 - 589
  • [10] *EPA, 1997, EPA452R97007, V5