New Borate-citrate: Synthesis, Structure, and Properties of Sr[B(C6H5O7)2](H2O)4•3H2O

被引：2

作者：

Wu, Hongping ^{[1
]}

Pan, Shilie ^{[2
]}

Jia, Dianzeng ^{[1
]}

Yu, Hongwei ^{[2
]}

Chen, Zhaohui ^{[1
]}

机构：

[1] Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China

[2] Chinese Acad Sci, Xinjiang Tech Inst Phys Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2012年 / 638卷 / 05期

基金：

中国国家自然科学基金;

关键词：

Sr[B(C6H5O7)2](H2O)4 center dot 3H2O; Single crystal growth; X-ray diffraction; Optical properties; NONLINEAR-OPTICAL PROPERTIES; CRYSTAL-STRUCTURE;

D O I：

10.1002/zaac.201100510

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of Sr[B(C6H5O7)2](H2O)4.3H2O, a new borate-citrate material, were grown with sizes up to 8X6X2 mm by slow evaporation of water at room temperature. The structure of Sr[B(C6H5O7)2](H2O)(4).3H2O was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/c, with a = 11.363(3) angstrom, b = 18.829(4) angstrom, c = 11.976(3) angstrom, beta = 110.736(3)degrees, and Z = 4. The SrO8 dodecahedra, BO4 tetrahedra and citrate groups are linked together to form chains. The compound was characterized by IR and UV/Vis/NIR transmittance spectroscopy as well as thermal analysis.

引用

页码：856 / 860

页数：5

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