Difunctionalization of Alkenes via the Visible-Light-Induced Trifluoromethylarylation/1,4-Aryl Shift/Desulfonylation Cascade Reactions

被引：127

作者：

Zheng, Lewei ^{[1
]}

Yang, Chao ^{[1
]}

Xu, ZhaoZhong ^{[1
]}

Gao, Fei ^{[1
]}

Xia, Wujiong ^{[1
]}

机构：

[1] Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, State Key Lab Urban Water Resource & Environm, Harbin 150080, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 80卷 / 11期

关键词：

DRIVEN PHOTOREDOX CATALYSIS; MEDIATED TRIFLUOROMETHYLATION; SYNTHETIC APPLICATIONS; ACTIVATED ALKENES; ORGANIC-SYNTHESIS; BOND FORMATION; PHOTOCATALYSIS; HYDROTRIFLUOROMETHYLATION; OXYTRIFLUOROMETHYLATION; FUNCTIONALIZATION;

D O I：

10.1021/acs.joc.5b00677

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel visible-light-induced trifluoromethylarylation/1,4-aryl shift/desulfonylation cascade reaction using CF3SO2Cl as CF3 source was described. The protocol provides an efficient approach for the synthesis of alpha-aryl-beta-trifluoromethyl amides and/or CF3-containing oxindoles as well as the isoquinolinediones under benign conditions.

引用

页码：5730 / 5736

页数：7

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