Lanthanide-Based Coordination Polymers With 1,4-Carboxyphenylboronic Ligand: Multiemissive Compounds for Multisensitive Luminescent Thermometric Probes

被引:43
作者
Abdallah, Ahmad [1 ]
Freslon, Stephane [1 ]
Fan, Xiao [1 ]
Rojo, Amandine [1 ]
Daiguebonne, Carole [1 ]
Suffren, Yan [1 ]
Bemot, Kevin [1 ]
Calvez, Guillaume [1 ]
Roisnel, Thierry [1 ]
Guillou, Olivier [1 ]
机构
[1] Univ Rennes, INSA Rennes, CNRS, UMR 6226,Inst Sci Chim Rennes, F-35000 Rennes, France
关键词
METAL-ORGANIC FRAMEWORKS; WHITE-LIGHT EMISSION; CRYSTAL-STRUCTURES; ENERGY-TRANSFER; 4-CARBOXYPHENYLBORONIC ACID; COMPLEXES; BRIGHTNESS; FAMILY; FLUORESCENCE; MODULATION;
D O I
10.1021/acs.inorgchem.8b02681
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reactions in water of lanthanide chlorides with the sodium salt of 1,4-carboxyphenylboronic acid lead to two series of isostructural compounds with respective general chemical formulas [Ln(cpb)(3)(H2O)(2)](infinity) for Ln = La or Ce and [Ln(cpbOH)(H2O)(2)center dot(cpb)](infinity) for Ln = Pr-Lu (except Pm) plus Y. Heterolanthanide coordination polymers that are isostructural to the second series have been synthesized, and their photophysical properties have been studied. This study evidences that it is possible to design multiemissive lanthanide-based coordination polymers that could find their application as multigauge luminescent thermometric probes.
引用
收藏
页码:462 / 475
页数:14
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